Question 3
Non polar compounds are travel faster on silica gel. Silica gel is generally used stationary phase and the empirical formula is SiO2. , The polar functional groups interacts strongly with the surface of silica gel particle while nonpolar functional groups are not interacting well. Polar compounds can interact through hydrogen bonds and dipole-dipole interactions.
Question 4
Polar compounds are interacting with polar solvents while non polar solvent interacting with non polar solvents. The mobile phase can be used in organic solvent or mixture of organic solvents. Hence the polar organic compounds only free to move with polar solvents .
Do polar or nonpolar compounds travel faster on silica gel? Explain 4. Do polar or nonpolar...
4. Do polar or nonpolar solvents have greater eluting ability? Explain
TLC Consider the following silica gel TLC plate of compounds A, B, and developed in hexanes: solvent front 0 D origin A B C 22. Determine the Ry values of compounds A, B, and Crun on a silica gel TLC plate using hexanes as the solvent. 23. Which compound, A, B, or C, is the most polar? 24. What would you expect to happen to the Ry values if you used acetone instead of hexanes as the eluting solvent? 25.TLC...
4. Consider the following silica gel TLC plac or compounds A, B, and hexines: developed in Fo-o- og a) Determine the Rr values of compounds A, B, and C run on a silica gel TLC plate using hexanes as the solvent b) Which compound, A, B, or C. is the most polar? values if you used acetone instead c) What would you expect to happen to the of hexanes as the eluting solvent? 5) Consider a sample that is a...
Ok, so what would happen if you are working with TLC and have a polar stationary phase (silica) and a mobile phase ( polar eluting solution) and you spot a nonpolar compound? Would the Rf values be greater than in a nonpolar mobile phase? I know in general if you are using TLC with polar silica and spot a nonpolar compound the nonpolar compound travels further (higher Rf values) because its chemical structure is different than the stationary phase compared...
which of the polar or nonpolar molecule travels faster in a column chromatography? explain
3) Consider the compounds trans-4-tert-butylcyclohexanol (1) and 4-tert-butylcyclohexanone (2) below. Using silica gel TLC plates, which of the two compounds will have the higher R value when dichloromethane is the developing solvent? Why? (5 pts).
Part A: Solubility of Organic Compounds in Polar and Nonpolar Solvents Data Table A1: Solubility of Some Common Organic Compounds Polar or Nonpolar? Solubility in H20 Solubility in CCIA Compound CH3CH2OH (ethanol) CH3(CH2), OH (1-octanol) (CH3CH2)2NH (diethylamine) CH(CH2),CH (pentane) CH3COCH (acetone) CH3COOH (acetic acid)
III. Lab 9 (pp. 131-135): Solubility of polar/nonpolar compounds in a given volume of polar/nonpolar solvents. 1. The solubility of 2-butanone (CH3CH2COCH3) in H2O is 25.6 g/100 mL H2O. By ratio and proportion, calculate the mass in g of 2-butanone that can be dissolved in 500 mL of H2O. 2. Thesolubilityoftetrahydrofuran(CH2)4OinH2Ois30.0g/100mLH2O.Byratioandproportion, calculate the mass in g of tetrahydrofuran that can be dissolved in 750 mL of H2O. 3. Thesolubilityofanantiobiotictilmicosininhexane(CH3(CH2)4CH3)is0.15g/100mLn-hexane. By ratio and proportion, calculate the mass in g of tilmicosin...
Post-Laboratory Questions Aspirin adnil tuleno Which compound turned out to be the most polar? The least polar? Do experimental results agree with your theoretical predictions? If not, why? 2. What would a chromatogram look like if a less polar developing solvent were used 3. Consider the following TLC plate of compounds A, B, and C developed in hexanes: solvent front starting line a) Determine the R values of compounds A, B, and C run on a silica gel TLC plate...
1. A mixture containing Compound X and Compound Y is analyzed using silica gel TLC. a. If Compound X has an Rf value of 0.7 and Compound Y has an Rvalue of 0.3, which compound is more polar? Explain. b. The solvent traveled 50 mm. How far did Compound Y travel? 2. Why isn't it reasonable for an R. value to be greater than 1? 3. How many spots would you expect to see if you conducted a TLC separation...