Ans 1
The balanced reaction
SO2 + 0.5O2 = SO3
Sulfur dioxide + oxygen = sulfur trioxide
Volume of oxygen gas = 69.2 L
Let pressure = P
Temperature = T
From the ideal gas equation
Moles of oxygen gas n = PV/RT = 69.2P/RT
From the stoichiometry of the reaction
0.5 mol O2 reacts with = 1 mol SO2
69.2P/RT mol O2 reacts with = 69.2P/0.5RT mol SO2
From the ideal gas equation
Volume of SO2 gas = nRT/P
= (69.2P/0.5RT)RT/P
= 138.4 L
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