A chemical formula of a molecule is the symbolic representation of the number of atoms present in that molecule. It gives the proportion of atoms present in the molecule and not the arrangement of atoms that are present in the chemical formula. Isomers are the molecules which have same chemical formula but different structural arrangement. The structure of the molecule can be obtained by verifying the presence of the number of unsaturation (double or triple bonds) and rings in the chemical formula through DBE calculation.
Nomenclature of organic molecules can be done by following IUPAC rules. IUPAC stands for International union of Pure and Applied chemistry. The IUPAC name of an organic molecule consists of three parts namely prefix, root word, and suffix.
• Double bond Equivalence (DBE) is calculated by the given formula:
Where Number of carbon atoms is denoted by C
Number of hydrogen atoms is denoted by H
Number of heteroatoms (other than carbon and hydrogen) is denoted by X
Number of nitrogen atoms is denoted by N
In general, alkanes do not contain any double or triple bonds.
• In IUPAC nomenclature, prefix represents the substituents present in the molecule.
Example :( methyl, ethyl, chloro, bromo etc...).
• Suffix represents the functional group present in the molecule.
Example: (ane for alkane, ene for alkene, yne for alkyne ol for alcohol, al for aldehyde etc.)
• Root word represents the longest carbon skeleton in the molecule.
The given chemical formula is .
Number of C present is 6.
Number of H present is 14.
The given chemical formula is .
Double bond Equivalence is calculated as follows.
The possible structural arrangement of atoms for the given molecular formula is shown below.
The longest carbon skeleton for the isomers is shown below.
The substituted isomers are assigned with numbers as follows.
Ans:
The structural isomers for the formula is
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