Question

Draw the organic product structure formed by the following reaction sequence.

Draw the organic product structure formed by the f

Draw the organic product structure formed by the following reaction sequence.

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Concepts and reason

A reaction is given with the reactant and a reagent whose correct product needs to be formed. The reactant is an alkene molecule which is reacting with diborane in the presence of hydrogen peroxide. The reaction is commonly called as hydroboration oxidation reaction of alkene and result in the formation of an alcohol.

Fundamentals

Alkenes generally reacts with the borane or diborane compounds and results in the addition reaction on double bonded carbon through syn addition. The addition reaction follows anti markovnikov’s rule, that is, negative part of the reagent gets attached to the carbon having more number of hydrogens as shown in the following example:

H
ВН,
Н.С.
н
1. BH3, diglyme
1. BH3, а
НАС
HC
Н;С
syn-addition product

Thus, the reaction forms syn product. Now, in the presence of hydrogen peroxide and strong base the above borane substituted product gets converted into corresponding alcohol molecule as shown below:

BH2
H
OH
-H
H3C-
IC
HO, OH, HO
HC
CH3
HỂ CH
oxidation product

The reaction collectively is known as hydroboration oxidation of alkene.

Draw the product of the reaction by using reagent 1, that is, addition of diborane or borane to the alkene group as shown below:

BHS
1. B Hdiglyme

Borane addition product react with the hydrogen peroxide to generate the corresponding alcohol as shown below:

BH
OH
2. H,02, OH, H20
Product

Ans:

Hence the final product of the reaction is as follows:

1. B2Hdiglyme
2. H202,OH, H20
Product

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