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18. Calculate the pH of a buffer solution that is 0.410 M in HOCI and 0.050M in NaOCI. [Ka(HOCI) 3.2 x 10* a. 0.39 d. 749 b.
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Answer #1

18) The pH is calculated:

pK = - log Ka + log [NaCl] / [HOCl] = - log 3.2x10 ^ -8 + log (0.05 / 0.41) = 6.58

19) The reaction of a weak acid and a weak base is d.

51) The concentration of the second ion in solution is equal to Ka2 = 6.1x10 ^ -5

52) The pOH and [OH-] are calculated:

pOH = 14 - 10.5 = 3.5

[OH-] = 10 ^ -3.5 = 3.2x10 ^ -4

You have Kb:

Kb = Kw / Ka = 10 ^ -14 / 4.9x10 ^ -10 = 2x10-5

The expression of Kb has:

Kb = [OH-] * [HCN] / [CN-]

2x10 ^ -5 = (3.2x10 ^ -4) ^ 2 / [CN-]

It clears [CN-] = 0.005 M

The mass of NaCN is calculated:

m NaCN = M * V * MM = 0.005 M * 0.25 L * 49 g / mol = 0.059 g

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