Provide the major product(s) for the following reactions: Show Stereochemistry when necessary
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
3. Predict the majoe product(s) for the following reactions. Show the stereochemistry of the product(s) when applicable. HCI (1) Hg(OAc)2 (2) NaBH4 (1) BH3 THF (2) H202. OH Br, Br2. H20 Pt (I) CH3CO3H (2) H,O+ (2) DMS HBr ROOR
3. Predict the major product(s) for the following reactions. (12 points) 1. BH3 THE 2. H2O2 NaOH Br2 H20 1. Hg(OAc)2 CH3OH 2. NaBH4 HBr
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr HBr (1 equivalent) (2 equivalents) Br2 Br2 (1 equivalent) CH2Cl2 (2 equivalents) CH2Cl2 HO HgSO4, H2SO4 1) disyamylborane 2) H202, NaOH, H2O
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). + Br2 Brain H20 1. 03 2. Mezs Hipo H/Pd 1. Hg(OAC) in THF/water 2. NaBH4, NaOH 1. BH3-THF 2. H2O2, NaOH peroxyacid HBO HBr/peroxide 1. Os04 2. NaHSO3
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i) Pd/C OsO4 NaHSO3, H20 н СHC1, КОН (iv) i) ВН, THF CECH in) H,О, NaOH Li, NH3 (liquid) (vi) XX H/H20 (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. он BH3, THF i)H202 NaOH он )Hg(OAc)2 H20 i)NaBH (iii CH O i) Zn/H +
Testbank Question 34 What is the major product for the following reaction? a. Hg(OAc)2. CH3OH NaBH4, NaOH +enanti omer +enanti omer он None of these choices. Testbank Question 39 What is the major product of the following reaction sequence? 1. H2, Pd/CaCO3. quinoline 2a BH3 THF 2b. H202, NaOH но он Гон Testbank Question 34 What is the major product for the following reaction? a. Hg(OAc)2. CH3OH NaBH4, NaOH +enanti omer +enanti omer он None of these choices. Testbank Question...
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). Br Br2 in H2O 1. O3 2. MegS HO H2/Pd OP A01018 1. Hg(OAc)2 in THF/Water 2. NaBH NaOH 1. BH3-THF 2. H2O2, NaOH estolqind, ( ym peroxyacid he anolbe o s HBr HBr/peroxide 1. OsO4 2. NAHSO3
4. Predict the products, Indicate stereochemistry when applicable а HBr H2S04 H20 1. Hg(OAC), H20 2. NaBH4 1.BH3 2. H2O2, NaOH> Br2 Cl2 H20