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<Chapter 7 Problem 7.41 The following reaction is used in the industrial synthesis of PVC polymer. C1 (9) + H2C - CH (9) CICH
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Answer #1

A)

There are gases only on reactant side.

So, there is more entropy on reactant side than on product side.

So, there is decrease in entropy

Delta S will be negative

Answer: option 2

B)

ΔGo = ΔHo - T*ΔSo

For reaction to be spontaneous, ΔGo should be negative

Here:

ΔHo is negative

ΔSo is negative

ΔGo will be negative at low temperature.

So, reaction is spontaneous only at low temperature.

Answer: option 3

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