If [Cu(H2016]++ is blue in solutions, select all of the following that could be yellow. [CuF6]4-...
Electronic absorption spectrum of copper ammine complexes (i) Draw the electron distribution in the d orbitals of an octahedral Cu(II) complex and show the electronic transition responsible for the absorptions observed. (ii) Assign the transition you observe for each complex and give the value of Δ (in cm-1). Visible absorption spectra of Cu(ll) complexes 1.2 Cu (H20)2(NH3)4 Cu (H2O)6 Cu (H20)3(NH3)3 0.8 0.6 Cu (H20)s(NH3) Cu (H20)4(NH3)2 0.4 0.2 850 500 550 600 650 700 750 800 900 450 nm...
2. Consider the following equilibrium represent by the reversible equation below: Cu²+(aq) + 4 NH4OH(aq) = [Cu(NH3)4]2+(aq) + 4 H2O(1) Blue Colorless Navy blue Predict the shift (explain why) and indicate the color of the solution when a. Drops of strong acid is added b. H2S gas is bubbled in the solution. Note: H2S reacts with transition metal cations.
2. Consider the following equilibrium represent by the reversible equation below: Cu?"(aq) + 4 NH OH(aq) = [Cu(NH3)4]?" (aq) + 4 H2O(1) Blue Colorless Navy blue Predict the shift (explain why) and indicate the color of the solution when a. Drops of strong acid is added b. H2S gas is bubbled in the solution. Note: H2S reacts with transition metal cations. c. Water is added to the mixture at equilibrium.
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
Select any and all of the following that Fe metal could be a reducing agent for Half-reaction E° (V) Aut te Au +1.69 +0.54 12 +2e - → 21- +0.34 Cu²+ + 2e- Cu -0.04 Fe3+ + 3e - Fe Zn2+ + 2e" - Zn -0.76 Natte - Na -2.71 Au 12 None of these o Cu²+ Zn2+
If a solution containing [Cu(NH3)4]2+ appears blue to your eyes, what color light is it absorbing? green violet orange blue
Which one of the following will transform the reactant into the product: Select one: A. 1) BH,/THF 2) H202/H20/0H B. H2O/Ni C. H2O/H,SO D. NaOH/H20 heat E. 1) Hg(OAc),/H,0 2) NaBH/OH
Select all of the following that you would predict to have a negative ΔS. a) 2 NO2 (g) → N2 (g) + 2 O2 (g) b) 2SO2 (g) + O2 (g) → 2 SO3 (g) c) 2 C6H6 (l) + 15 O2 (g) → 12 CO2 (g) + 6 H2O (g) d) 4 NO (g) + 6 H2O (g) → 4 NH3 (g) + 5 O2 (g) e) 2 BF3 (g) + 3 CaO (s) → B2O3 (s) + 3...
balance equations please or fix them Chemical Equations: ) Bi, Cu(HO2+NH OHCu(NH,), 4 (white)+ Bi(OH), (blue) 2) CdCl2, HS NH OH CHNSheat CdS (yellow) 3) Sn(OH2HCI CHNS heat SnS (yellow)
2. Consider the following equilibrium: Cu2+(aq) pale blue + 4NH3(aq) +[Cu(NH3)4]2+ (aq) colorless deep purple Would you expect to see an increase, no change, or a decrease in the purple color when: (a) the temperature of the system is increased (the reaction is endothermic). (b) a catalyst is added. (c) more aqueous NH3 is added to the equilibrium. (d) the pressure is increased. NaOH(aq) is added to the system, resulting in the precipitation of Cu(OH)2(s). _(1) (f) the volume of...