1. Classify each reaction as substitution (S), elimination (E), or addition (A).
2. Draw out the reaction steps shown based on the curved arrows.
3. Based on the table of concentrations below, determine the order for each reactant, and the overall order of the reaction. A + B --> C
![[A] [B] Relative rate 1.0 1.0 1.0 3.0 1.0 9.0 3.0 2.0 18](http://img.homeworklib.com/questions/bf495d00-70da-11ea-8769-6b62c5e71182.png?x-oss-process=image/resize,w_560)
Homework Answers
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1. Classify each reaction as substitution (S), elimination (E),
or addition (A).
2. Draw out the...
1. Classify each of the following reactions as either an addition, elimination, substitution, or rearrangement ОН...
1. Classify each of the following reactions as either an addition, elimination, substitution, or rearrangement ОН SOCI, Br Br2 1 equiv. Br ОН Он H,SO, + H20 heat ОН CH* 1. OsO4, 2. Н,О, "ОН molten KOH 200°C Br Br
Q3. Classify each transformation as substitution, elimination, or addition HO OH (1 point) CO2 b. O...
Q3. Classify each transformation as substitution, elimination, or addition HO OH (1 point) CO2 b. O co 00 02 OH Q5. (2 point) Draw the transition state for the following reaction. H2O H3O* Use full-headed or half-headed curved arrows to show the movement of electrons in each reaction. | 6: đi: b. V + Bra - 8
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH...
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH + HCN– CH3-CH-CN CH3-CH2-CH2-OH + HBr – CH3-CH2-CH2-Br + H2O CH3-CH=CH-CH3 + HBr – CH3-CH-CH2-CHz Br
Complete and classify each reaction as substitution, elimination, or neither. Identify the lea group in each...
Complete and classify each reaction as substitution, elimination, or neither. Identify the lea group in each reaction, and the nucleophile in substitutions. 18pts 1. Na+-OCH Br H,SO4 он- KI Br show how Diels-Alder reactions might be used to synthesize the following compounds. 30pts CH
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3...
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
A. Classify organic reaction below as either addition, elimination, rearrangement or substitution. For each reaction predict...
A.
Classify organic reaction below as either addition, elimination,
rearrangement or substitution. For each reaction predict whether
deltaS>0, deltaS<0, delta S~0
B. For reaction iv the equilibrium constant has been measured
as K=195. Calculate deltaG for this reaction at 25deg C giving
answer in KJ/mil. ( the most convenient form of R for this
calculation is R=8.314J/mol/K.
C. Using answer to (b) and (c) predict the sign of deltaH for
reaction (iv)
Cl OH +C Br + 2 HBr Br...
angement 1) Classify each of the following reactions as elimination, substitution, addition or r 2) Classify...
angement 1) Classify each of the following reactions as elimination, substitution, addition or r 2) Classify each of the following sites as electrophilic or nucleophilic
5.59. The following equations represent (a) an addition reaction, (b) a substitution reaction, (c) an elimination...
5.59. The following equations represent (a) an addition reaction, (b) a substitution reaction, (c) an elimination reaction, and (d) a rearrangement. Calculate for each, and compare amongst the various reactions (i) the atom efficiencies for atoms of each element, (ii) the overall atom efficiency, and (iii) the E-factor. In calculating the E-factor, state your assumption about which is the desired product. Br а. Br2 Br Н С. b. Н.С ОН Br H20 HBr Br с. ""CHз CH,CH2O-Na Н.С CH3 CH3...
1. (2 pts) Classify the reaction below. (circle the best answer) A. Substitution B. Elimination C....
1. (2 pts) Classify the reaction below. (circle the best answer) A. Substitution B. Elimination C. Addition D. none of the above 2. (2 pts) Classify the reaction below. (circle the best answer) OTs OH A. Substitution B. Elimination C. Addition D. none of the above 3. (2 pts) Classify the reaction below. (circle the best answer) OH OH A. Substitution B. Elimination C. Addition D. none of the above
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction CH3-CH2-CH2-CH3 +...
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction CH3-CH2-CH2-CH3 + Cl2 → CH2-CH2-CH2-CH3 + HCI CI CH3-CH=CH-CH3 + Cl2 → CH3-CH-CH-CH3 CICI CH3-CH2-CH-CH3 - CH3-CH2-CH=CH2 + HCI
1. Classify each of the following reactions as either an addition, elimination, substitution, or rearrangement ОН SOCI, Br Br2 1 equiv. Br ОН Он H,SO, + H20 heat ОН CH* 1. OsO4, 2. Н,О, "ОН molten KOH 200°C Br Br
Q3. Classify each transformation as substitution, elimination, or addition HO OH (1 point) CO2 b. O co 00 02 OH Q5. (2 point) Draw the transition state for the following reaction. H2O H3O* Use full-headed or half-headed curved arrows to show the movement of electrons in each reaction. | 6: đi: b. V + Bra - 8
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH + HCN– CH3-CH-CN CH3-CH2-CH2-OH + HBr – CH3-CH2-CH2-Br + H2O CH3-CH=CH-CH3 + HBr – CH3-CH-CH2-CHz Br
Complete and classify each reaction as substitution, elimination, or neither. Identify the lea group in each reaction, and the nucleophile in substitutions. 18pts 1. Na+-OCH Br H,SO4 он- KI Br show how Diels-Alder reactions might be used to synthesize the following compounds. 30pts CH
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
A.
Classify organic reaction below as either addition, elimination,
rearrangement or substitution. For each reaction predict whether
deltaS>0, deltaS<0, delta S~0
B. For reaction iv the equilibrium constant has been measured
as K=195. Calculate deltaG for this reaction at 25deg C giving
answer in KJ/mil. ( the most convenient form of R for this
calculation is R=8.314J/mol/K.
C. Using answer to (b) and (c) predict the sign of deltaH for
reaction (iv)
Cl OH +C Br + 2 HBr Br...
angement 1) Classify each of the following reactions as elimination, substitution, addition or r 2) Classify each of the following sites as electrophilic or nucleophilic
5.59. The following equations represent (a) an addition reaction, (b) a substitution reaction, (c) an elimination reaction, and (d) a rearrangement. Calculate for each, and compare amongst the various reactions (i) the atom efficiencies for atoms of each element, (ii) the overall atom efficiency, and (iii) the E-factor. In calculating the E-factor, state your assumption about which is the desired product. Br а. Br2 Br Н С. b. Н.С ОН Br H20 HBr Br с. ""CHз CH,CH2O-Na Н.С CH3 CH3...
1. (2 pts) Classify the reaction below. (circle the best answer) A. Substitution B. Elimination C. Addition D. none of the above 2. (2 pts) Classify the reaction below. (circle the best answer) OTs OH A. Substitution B. Elimination C. Addition D. none of the above 3. (2 pts) Classify the reaction below. (circle the best answer) OH OH A. Substitution B. Elimination C. Addition D. none of the above
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction CH3-CH2-CH2-CH3 + Cl2 → CH2-CH2-CH2-CH3 + HCI CI CH3-CH=CH-CH3 + Cl2 → CH3-CH-CH-CH3 CICI CH3-CH2-CH-CH3 - CH3-CH2-CH=CH2 + HCI
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