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Be sure to answer all parts. Determine which of the following H atom electron transitions has the longest wavelength and whic
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Answer #1

Using Rydberg formula:

1/λ = R× Z2(1/n12 - 1/n22)
where

λ = wavelength of the photon
R = Rydberg's constant (1.097 x 107 m-1)
Z = atomic number of the atom = For hydrogen,Z = 1
n1 and n2 are integers to denote orbits where n2 > n1

(a) n1 = 1 , n2 = 4

1/λ = 1.097 × 107 × ( 1/12 - 1/42)

λ = 9.72 × 10-8 m

(b) n1 = 4 , n2 = 8

1/λ = 1.097 × 107 × ( 1/42 - 1/82)

λ = 1.94 × 10-6 m

(c) n1 = 4 , n2 = 9

1/λ = 1.097 × 107 × ( 1/42 - 1/92)

λ = 1.81 × 10-6 m

(d) n1 = 1 , n2 = 12

1/λ = 1.097 × 107 × ( 1/12 - 1/122)

λ = 9.17 × 10-8 m

So the longest wavelength photon is (b) λ = 1.94 × 10-6 m

So the shortest wavelength photon is (d) λ = 9.17 × 10-8 m

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