Question

4. A low oxidation state organometallic complex contains -acceptor ligands and the metal center tends to...

4. A low oxidation state organometallic complex contains -acceptor ligands and the metal center tends to
acquire 18 electrons in its valence shell, thus filling the valence orbitals. This is known as the 18-electron
rule. Show that Mo(CO)6 obeys the 18-electron rule.

0 0
Add a comment Improve this question Transcribed image text
Answer #1

Mo CL) 2 e denor In the iven mplex; Co iA Jigand Eledron Lahuahion Kr] 4d5 MD The d and Ss electaons Mo ptipas bonding. Mnaat

Add a comment
Know the answer?
Add Answer to:
4. A low oxidation state organometallic complex contains -acceptor ligands and the metal center tends to...
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
  • Show the metal center in each of the following obeys the 18-electron rule Fe(CO)5 2. Show...

    Show the metal center in each of the following obeys the 18-electron rule Fe(CO)5 2. Show that the metal center in each of the following one 2.1) Fe(CO) of the following obeys the 18-electron rule (10 Pt.) Oxidation state of each metal center is 2.2) Ni(CO)4 Oxidation state of each metal center is 2.3) [Mn(CO)s] Oxidation state of each metal center is 2.4) Mo(CO), Oxidation state of each metal center is

  • , determine the formal oxidation state of the transition metal and the corresponding number of d electrons. State whether each one is likely to be stable enough to be characterized.

    Q1) For each of the following compounds, determine the formal oxidation state of the transition metal and the corresponding number of d electrons. State whether each one is likely to be stable enough to be characterized. (1) [Re(CO)5]     (2) [HFe(CO)4]-       (3)  ((ŋ6-C5H5)2Fe)    (4) ((ŋ6-C6H6)2Cr)      (5) ((ŋ5-C5H5)ZrCl(OCH3)      (6) (IrCl(PPh3)3)     (7) (Mo(CO)3(PPh3)3)      (8) (Fe(CO)4(C2H4))     (9) (W(CO)5Cl)-     (10) Ni(CO)4)Q2) Use the 18-electron rule to predict the number of carbonyl ligands, n, in each of the following complexes:     (1) [Cr(CO)n]     (2) [Fe(CO)n(PPh3)2)]  (3) [Mo(CO)n(PMe3)3]           ...

  • 2. For each of the following compounds, 1) write the formal oxidation state of the transition...

    2. For each of the following compounds, 1) write the formal oxidation state of the transition metal and 2) the corresponding number of d electrons. 3) State whether or not each one is likely to be stable enough to be characterized. (a) [Re(CO)5] (b) [Cr(η6 -C6H6)2] (c) [Mo(CO)3(PPh3)3] (d) [Fe(η2 -C2H4)(CO)4] (e) [Zr(η5 -C5H5)Cl(OH)] (f) [Co(η5 -C5H5)2] 3. Identify the first-row transition metal (M) that follows the 18-electron rule for each of the following compounds (show how you arrived at...

  • 2. For each of the following compounds, 1) write the formal oxidation state of the transition met...

    2. For each of the following compounds, 1) write the formal oxidation state of the transition metal and 2) the corresponding number of d electrons. 3) State whether or not each one is likely to be stable enough to be characterized. (a) [Re(CO)5] (b) [Cr(η6 -C6H6)2] (c) [Mo(CO)3(PPh3)3] (d) [Fe(η2 -C2H4)(CO)4] (e) [Zr(η5 -C5H5)Cl(OH)] (f) [Co(η5 -C5H5)2] 3. Identify the first-row transition metal (M) that follows the 18-electron rule for each of the following compounds (show how you arrived at...

  • In 1984, the first organometallic compounds with H2 as an ?2 ligand were synthesized: M(CO)3(PR3)2(H2) with...

    In 1984, the first organometallic compounds with H2 as an ?2 ligand were synthesized: M(CO)3(PR3)2(H2) with M = Mo or W and R = cyclohexyl or isopropyl. These complexes illustrate back-bonding with H2 as a ligand. a. Draw a structure for this molecule (just use R for the substituents on the P atoms). Because the R groups are very bulky, assume that the two PR3 ligands are in a trans configuration. Only one isomer is then possible. Show that this...

  • please only answers for questions 1-23. No work needed 1) Give the ground state electron configuration...

    please only answers for questions 1-23. No work needed 1) Give the ground state electron configuration for the ion of Ba. A) [Krj5s24d 105pfes2 B) (KrjS24d105ph26p2 9(KrjS24d105p6 D) Kr525p E) [Kr]5s24d105pés 2) Choose the valence orbital diagram that represents the ground state of Se A) 1 11 1 4s 4p в) 1 11 4s 4p C) 1L 3s Зр D) 11 1L 1 3s Зр E) 1 1 4s 4P 3) How many valence electrons do the alkaline earth metals...

ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT