What is the "AXE" description of the fluoroform CHF3 molecule?
Arriving at AXE description of any molecule is very simple. It is mostly used when we work with VSEPR theory. There is an AXE description or notation for each geometry because it mainly centres around the geometry of a molecule.
A - indicates the central atom
X - indicates the atoms attached to the central atom and the number of atoms attached to the central atom is denoted as a subscript to X.
E - indicates the number of lone pairs on the central atom
For example - CH4.
Central atom is carbon , C and 4 H are attached to it and it is a stable molecule with 8 electrons that is octet configuration and hence no lonepairs on C. It is an example of a tetrahedral molecule. So all molecules with tetrahedral geometry has AXE notation as AX4.
Now CHF3 is also a molecule with tetrahedral geometry so without a doubt it also has a notation of AX4.
Examples,
BF3 - has 3 electrons in its outer shell - all 3 are shared with F- so no lonepair left - hence AX3 - BF3 has a triagonal planar geometry hence all molecules with a triagonal planar geometry will be AX3.
Now lets consider PCl3 - has 5 electrons in its outer shell as it belongs to the nitrogen family - 3 electrons are shared with Cl (chlorine) - 2 electrons are non bonded or free hence it is a lone pair - so the AXE notation is AX3E1.
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Molecule Type Shape Electron Arrangement Geometry Examples AX, E, Trigonal bipyramidal AXE Sqaure Pyramidal CIF,, BIF AXE Octahedral + Electron arrangement including fone pairs, shown in pale yellow Observed grometry (excluding lone pairs) Taken from http://en.wikipedia.org/wiki/AXE_method#AXE_Method on 7-11-2010. PROCEDURE Draw the Lewis Dot-Dash Structure of the molecules and ions below. Indicate the AXE notation, a Lewis structure (or one of the possibilities), and the electron and molecular geometry of the underlined atom, Molecule AXE Notation Lewis Structure Electron Geometry Molecular...
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