[10 pts] For the cyclic alkane depicted in the box, draw the two chair conformations on...
please help II. (8 pts.) Draw both possible chair conformations of the following compound as sawhorse projections. Show all substituents on the substituted positions of the ring. Each structure will be graded as right or wrong (no partial credit), so do your very best. OH III. (12 pts.) Give the expected major product for each reaction. Show any stereochemistry clearly. HCI, room temp (1 equiv.) 1) H2 Lindlar catalyst 2) BH3
1. (a) Draw the two chair conformations for this molecule. (3 pts) (b) Label the more stable conformation (1 pt) 2. Provide (RS)-designations for the two starred (1) stereogenic centers (3 pts) 3. Use a Newman projection to draw the most stable conformation for the C(3)-C(4) bond in this molecule. (3 pts) OH 3-fluoro-3-methylpentan-1-ol
5) Draw the two chair conformations (using stick drawings) for trans-3-tert-butyl-1- isopropylcyclohexane. (10 pts) 6) Draw the Newman Projections for the two chair conformations of trans-3-tert-butyl-1- isopropylcyclohexane. (10 pts)
(10 pts) Draw the following two structures, A and B in their lowest energy chair conformations. Be sure to carefully label your structures as A, B when you draw them. CH3 H3COCH3 Br
6. Draw the two chair conformations for cis-1-sec-butyl-2-ethylcyclohexane. Predict the most stable conformer and draw the corresponding Newman projection (4 pts) 7. Convert the following compounds from their 3D structure to their Fisher projection and vice-versa (4 pts) НО Br HO co₂me HN CI CO2Me НО -СІ НЕОН СН2ОН 5| Page 8. The specific rotation for (R)-methyl 2-chloro-2,3-dihydroxypropanoate is -126.7. A student prepare a sample of methyl 2-chloro-2,3-dihydroxypropanoate enantiomers that shows a specific rotation of +89.6, (a) Calculate the percent...
8 Draw your two products (each in the most stable chair conformation) below using the numbering provided Show only the OH and terr-butyl groups on the ring a) label cach group as equatorial (eq) or axial (x). b) label each group as top face (top) or bottom face (bot). trans-4-tert-butylcyclohexanol cis 4-tert-butylcyclohexanol 9. When looking at the two compounds prepared in this reduction, which compound is more stable, cis or trans? Circle your answer. 10) Draw the most stable chair...
PLEASE HELP WITH ALL. A. Which of the following Newman projections would represent the least stable conformer of 2,2,3.3-tetramethylbutane, looking down the 2,3 bond? H3C H3C H3C H3C CH3 b) CH3 H3C e) a) c) CH3 H3C CH3 CH CH3 CH о он B. which one of the following compounds would be chiral? Br он о он a) но HO O он HO C C. which of the following could potentially be used to distinguish between enantiomers? b) NMR c)...
18. Which of the following compound(s) would undergo mutarotation in aqueous solution? 19. Draw the chair conformation of a-D-galactopyranose. 20. Which of the following compound(s) is a glycoside? 21. Provide the reagents neccesary to carry out the following conversion. 22. Predict the product(s) for the following reaction. 23. D-glucose & D-galactose are ______epimers of each other. 24. Predict the product(s) for the following reaction. 25. Which of the following compound(s) would produce D-glucose and D-mannose when treated with HCN followed...
1. [10 pts] Consider the elimination reaction for the following alkyl halide with sodium methoxide in methanol (Na* OCH, CH,OH). CH NaOme MeOH CH Compound A Problem 2c Draw the major expected organic product (a) Redraw Compound A as seen in Viewpoint I below left as a Newman projection on the template provided in Problem 2a (below). Hint: Fill in missing Hs ar C2 and C3 to help you get started! (b) Rotate the C2 C3 bond to obtain the...