Homework Answers
PCC is pyridinium chlorochromate and PDC is pyridinium dichromate , both are specifically used for oxidation of 1° alcohol to aldehyde and 2° alcohol to ketone .
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11) Using only reactions learned in class, Synthesize the following products from the starting that are...
) Using only reactions learned in class, synthesize the following products from the starting materials that...
) Using only reactions learned in class, synthesize the following products from the starting materials that are shown using organic compounds that contain no more than two carbons. More than one step will be required. Show all reagents and intermediates along your synthetic pathway (10 points). HO Ph Ph
17. Outline the reactions necessary to accomplish the synthesis of the following compound starting from benzene....
17. Outline the reactions necessary to accomplish the synthesis of the following compound starting from benzene. Provide the necessary reagents/reactants and include the structure of intermediate organic products. Any additional organic starting materials used (excluding solvents) must not contain more than 3 carbons. You do not need to provide the mechanism of each reaction. ОН 18. Outline the reactions necessary to accomplish the synthesis of the following compound. Provide the necessary reagents/reactants and include the structure of intermediate organic products....
b) Propose a reasonable synthetic route to synthesize the following products from the given starting material....
b) Propose a reasonable synthetic route to synthesize the following products from the given starting material. Draw all isolated intermediates and include all reagents used in each step. 1. CI OH مت 2. 3. Br OH -OH
8. Predict the number of peaks and the 'H splitting (multiplicity) for the following compound: он...
8. Predict the number of peaks and the 'H splitting (multiplicity) for the following compound: он Outline the synthetic steps necessary to synthesize the compound below. You may use any organic or inorganic reagents you need but no more than 3 carbons starting compounds. Show the structures of all intermediate compounds that would probably be isolated during the course of your synthesis, and show all necessary reagents 9.
4. Predict the products of the following reactions o O 1. H3C-C-O-C-CH ?? C. d. DMSO...
4. Predict the products of the following reactions o O 1. H3C-C-O-C-CH ?? C. d. DMSO CH2Ch H3 heat (draw all intermediates) 5. As a certification of your hard work, design a synthesis for 1-ethylcyclohexanol from cyclohexane. You can use any inorganic reagents, solvents, and any organic reagents provided they contain no more than two carbons.
Synthesize the following reactions using the starting materials given using any reagents necessar...
Synthesize the following reactions using the starting materials
given using any reagents necessary
Using the starting materials on the left of the arrows synthesize
the product on the right using any reagents necessary to complete
the reaction
Noz Br
Noz Br
#4 is asking for a potential path to synthesize from the listed starting material to the...
#4 is asking for a potential
path to synthesize from the listed starting material to the final
product. Including all reagents used and intermediary steps. The
chapter this was assigned with is enolate anions & amines.
1. Draw all possible products for the base catalyzed reaction of ethanal and propanal. Indicate the new bond formed. (Full: all possible products and correct ID of new bond, partial: 75% of possible products) 2. Draw and label the kinetic and thermodynamic products for...
Synthesize the following compounds from the given starting material. You may add on any alkyl/alkyl halide...
Synthesize the following compounds from the given starting material. You may add on any alkyl/alkyl halide under 6 carbons or any necessary inorganic reagent needed (this includes triphenyl phosphine (Ph3P). Draw all intermediates and reagents necessary to reach product. OH tar
Show how you would synthesize the following compound starting with acetylene and compounds containing no more...
Show how you would synthesize the following compound starting
with acetylene and compounds containing no more than two carbon
atoms as organic starting material. You may use any additional
reagents you need
Br H H Br
11. The following transformations can not be performed in one step. Provide a sequence of reactions...
11. The following transformations can not be performed in one step. Provide a sequence of reactions to convert the "starting material to the "product." Show all the reagents and synthetic intermediates. NO MECHANISMS PLEASE!
) Using only reactions learned in class, synthesize the following products from the starting materials that are shown using organic compounds that contain no more than two carbons. More than one step will be required. Show all reagents and intermediates along your synthetic pathway (10 points). HO Ph Ph
17. Outline the reactions necessary to accomplish the synthesis of the following compound starting from benzene. Provide the necessary reagents/reactants and include the structure of intermediate organic products. Any additional organic starting materials used (excluding solvents) must not contain more than 3 carbons. You do not need to provide the mechanism of each reaction. ОН 18. Outline the reactions necessary to accomplish the synthesis of the following compound. Provide the necessary reagents/reactants and include the structure of intermediate organic products....
b) Propose a reasonable synthetic route to synthesize the following products from the given starting material. Draw all isolated intermediates and include all reagents used in each step. 1. CI OH مت 2. 3. Br OH -OH
8. Predict the number of peaks and the 'H splitting (multiplicity) for the following compound: он Outline the synthetic steps necessary to synthesize the compound below. You may use any organic or inorganic reagents you need but no more than 3 carbons starting compounds. Show the structures of all intermediate compounds that would probably be isolated during the course of your synthesis, and show all necessary reagents 9.
4. Predict the products of the following reactions o O 1. H3C-C-O-C-CH ?? C. d. DMSO CH2Ch H3 heat (draw all intermediates) 5. As a certification of your hard work, design a synthesis for 1-ethylcyclohexanol from cyclohexane. You can use any inorganic reagents, solvents, and any organic reagents provided they contain no more than two carbons.
Synthesize the following reactions using the starting materials
given using any reagents necessary
Using the starting materials on the left of the arrows synthesize
the product on the right using any reagents necessary to complete
the reaction
Noz Br
Noz Br
#4 is asking for a potential
path to synthesize from the listed starting material to the final
product. Including all reagents used and intermediary steps. The
chapter this was assigned with is enolate anions & amines.
1. Draw all possible products for the base catalyzed reaction of ethanal and propanal. Indicate the new bond formed. (Full: all possible products and correct ID of new bond, partial: 75% of possible products) 2. Draw and label the kinetic and thermodynamic products for...
Synthesize the following compounds from the given starting material. You may add on any alkyl/alkyl halide under 6 carbons or any necessary inorganic reagent needed (this includes triphenyl phosphine (Ph3P). Draw all intermediates and reagents necessary to reach product. OH tar
Show how you would synthesize the following compound starting
with acetylene and compounds containing no more than two carbon
atoms as organic starting material. You may use any additional
reagents you need
Br H H Br
11. The following transformations can not be performed in one step. Provide a sequence of reactions to convert the "starting material to the "product." Show all the reagents and synthetic intermediates. NO MECHANISMS PLEASE!
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