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1. For each pair of compounds identify which compound can be more readily deprotonated and explain...
identify which compound is more acidic and explain your choice. or each of the following compounds,...
identify which compound is more acidic and explain your choice. or each of the following compounds, Make sure you include structures of these which compounds in your answers ounds, 1. F (e) 24-Dimethy-3,5-hepanedione or 4, 4-Dimethy)-3,5-heptanedione (b) 1.2-Cyclopentanedione or 1,3-cyclopentanedione 2. When 2-hepten-4-one is treated with LDA, a proton is removed from one of the gamma (z) positions. identily which gamma position is deprotonated, and explain why the y proton is the most acidie proton in the compound. 3. Rank...
3) Identify the reagents that you would use to produce the following compounds using a Claisen...
3) Identify the reagents that you would use to produce the
following compounds using a Claisen condensation.
4) For the following reaction, predict the major product and
propose a mechanism for its formation.
3. Identify the reagents that you would use to produce the following compounds using a Claisen condensation. 4. For each of the following reactions, predict the major product and propose a mechanism for its formation. 1) LDA. 2) CHal
Name: Assuming each compound is planar, state which of the following compounds are aromatic for each...
Name: Assuming each compound is planar, state which of the following compounds are aromatic for each say why (8 points) b) Using curved arrows show how two more resonance structure can be derived for the following (show the derived structure). (2 points) 2. Considering the effect of the substituent on the benzene ring below. Identify the major product of the following reaction. (20 points) a. (5 points) Br2 FeBrg b. What is the active Electrophile for this reaction? (3 points)...
Name: 3 1. Assuming each compound is planar, state which of the following compounds are aromatic...
Name: 3 1. Assuming each compound is planar, state which of the following compounds are aromatic and for each say why (8 points). a. b. d. C. HON b) Using curved arrows show how two more resonance structure can be derived for the following (show the derived structure). (2 points) d 2. Considering the effect of the substituent on the benzene ring below. Identify the major product of the following reaction. (20 points) a. (5 points) Hat Аневи Br2 FeBr3...
12 Identify the compound showing following infrared spectrum 15 Identify the reaction CH2OH sequence for the...
12 Identify the compound showing following infrared spectrum 15 Identify the reaction CH2OH sequence for the following transformation. CH (A) (B) CH3CI KMnO4, H" CH COCI LIAH AICI: AICI: Br2 CH3COCI HOCH2CH2OH Mg FeBry AICI, H30+ ether CH20 H307 wavumber om (B) (A) Хон (C) (D) Mg. Å CH,COCI H30 ОН (C) Br2 FeBry ether AICI CH3COCI BEZ Mg CH20 H30* AICI; FeBry ether (D) 13 A factor which explains the large difference in the boiling point of OCH OH...
Draw the structure of each compound 1. Draw the structure of each compound: (a) cis-1,2-Cyclohexanediol (b)...
Draw the structure of each compound
1. Draw the structure of each compound: (a) cis-1,2-Cyclohexanediol (b) Isobutanol (c) 2,4,6-Trinitrophenol (d) (R)-2,2-Dimethyl-3-heptanol (e) Ethylene glycol (0) (s)-2-Methyl-1-butanol 2. Acid-catalyzed hydration of 3,3-dimethyl-1-butene produces 2,3-dimethyl-2-butanol. Show a mechanism for this reaction 3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain. 4. Using 2-propanol as your only source of carbon, show how you would prepare 2-methyl- 2-pentanol. 5. Identify...
Question 1 Not yet answered Points out of 3.00 Consider two compounds shown below. For each compo...
Answer all questions please. Not due until April 3rd.
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Question 1 Not yet answered Points out of 3.00 Consider two compounds shown below. For each compound identify which group is the most acidic, the least acidic, or has mid acidity value (pKa value) он он 1 HO 0H3 Flag question NH3 OH 2 group 1 Choose... group 2 Choose group 3 Chse... group I group IIChoose group III Choose... Choose. Question 2 Not yet answered Points out of 3.00...
Chem 2200 E1/E2 Practice Problems tn 1. Predict the major produc t in each of the...
Chem 2200 E1/E2 Practice Problems tn 1. Predict the major produc t in each of the following reactions Ha OEt b) Br Ph 2. When 1-chloro-oox(Compound I) is treated with sodium methoxide in methanol, elimination readily occurs to give 1,2-x0oxd compound I). However, the two diastereomers of i (la and lb) each give one single isomer of il (either lla or lib) as shown below. Provide structures for la and ib as well as a mechanistic explanation for the stereopecificity....
14) 8 Provide the proper IUPAC name for the compounds below complete sentences, explain your choice...
14) 8 Provide the proper IUPAC name for the compounds below complete sentences, explain your choice 45) 6 Cirele the stronger base in the pair below. Using structures and 1-2 46) 14 Provide a detailed, stepwise mechanism for the following rea ction for the major produet AICI, 47) 14 From the following spectrosopic data, provide a structure. Clearly show/calculate/indicate: 1) the elements of unsaturation 2) major peaks/stretches in the IR spectrum 3) the total number of different types of carbons,...
Which of the following compounds can have cis and trans isomers? 2-Methyl-2-butene Propene 0 1-Butene 1,2-Dichloro-1-Bu...
Which of the following compounds can have cis and trans isomers? 2-Methyl-2-butene Propene 0 1-Butene 1,2-Dichloro-1-Bu What is the correct molecular formula of 2,4-Diethyltouleno OCHA 0 C₂ H₂2 G H C:oH20 18 Which of the following compounds can have cis and trans isomers? 1-Butene 2-Methyl-2-butene 1,2-Dichloro-1-Butene Propene CH3CHBr2 is obtained from O Reaction of ethyne with one mole of HBr O Reaction of ethyne with one mole of Br2 Reaction of ethyne with two moles of Br2 Reaction of ethyne...
identify which compound is more acidic and explain your choice. or each of the following compounds, Make sure you include structures of these which compounds in your answers ounds, 1. F (e) 24-Dimethy-3,5-hepanedione or 4, 4-Dimethy)-3,5-heptanedione (b) 1.2-Cyclopentanedione or 1,3-cyclopentanedione 2. When 2-hepten-4-one is treated with LDA, a proton is removed from one of the gamma (z) positions. identily which gamma position is deprotonated, and explain why the y proton is the most acidie proton in the compound. 3. Rank...
3) Identify the reagents that you would use to produce the
following compounds using a Claisen condensation.
4) For the following reaction, predict the major product and
propose a mechanism for its formation.
3. Identify the reagents that you would use to produce the following compounds using a Claisen condensation. 4. For each of the following reactions, predict the major product and propose a mechanism for its formation. 1) LDA. 2) CHal
Name: Assuming each compound is planar, state which of the following compounds are aromatic for each say why (8 points) b) Using curved arrows show how two more resonance structure can be derived for the following (show the derived structure). (2 points) 2. Considering the effect of the substituent on the benzene ring below. Identify the major product of the following reaction. (20 points) a. (5 points) Br2 FeBrg b. What is the active Electrophile for this reaction? (3 points)...
Name: 3 1. Assuming each compound is planar, state which of the following compounds are aromatic and for each say why (8 points). a. b. d. C. HON b) Using curved arrows show how two more resonance structure can be derived for the following (show the derived structure). (2 points) d 2. Considering the effect of the substituent on the benzene ring below. Identify the major product of the following reaction. (20 points) a. (5 points) Hat Аневи Br2 FeBr3...
12 Identify the compound showing following infrared spectrum 15 Identify the reaction CH2OH sequence for the following transformation. CH (A) (B) CH3CI KMnO4, H" CH COCI LIAH AICI: AICI: Br2 CH3COCI HOCH2CH2OH Mg FeBry AICI, H30+ ether CH20 H307 wavumber om (B) (A) Хон (C) (D) Mg. Å CH,COCI H30 ОН (C) Br2 FeBry ether AICI CH3COCI BEZ Mg CH20 H30* AICI; FeBry ether (D) 13 A factor which explains the large difference in the boiling point of OCH OH...
Draw the structure of each compound
1. Draw the structure of each compound: (a) cis-1,2-Cyclohexanediol (b) Isobutanol (c) 2,4,6-Trinitrophenol (d) (R)-2,2-Dimethyl-3-heptanol (e) Ethylene glycol (0) (s)-2-Methyl-1-butanol 2. Acid-catalyzed hydration of 3,3-dimethyl-1-butene produces 2,3-dimethyl-2-butanol. Show a mechanism for this reaction 3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain. 4. Using 2-propanol as your only source of carbon, show how you would prepare 2-methyl- 2-pentanol. 5. Identify...
Answer all questions please. Not due until April 3rd.
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Question 1 Not yet answered Points out of 3.00 Consider two compounds shown below. For each compound identify which group is the most acidic, the least acidic, or has mid acidity value (pKa value) он он 1 HO 0H3 Flag question NH3 OH 2 group 1 Choose... group 2 Choose group 3 Chse... group I group IIChoose group III Choose... Choose. Question 2 Not yet answered Points out of 3.00...
Chem 2200 E1/E2 Practice Problems tn 1. Predict the major produc t in each of the following reactions Ha OEt b) Br Ph 2. When 1-chloro-oox(Compound I) is treated with sodium methoxide in methanol, elimination readily occurs to give 1,2-x0oxd compound I). However, the two diastereomers of i (la and lb) each give one single isomer of il (either lla or lib) as shown below. Provide structures for la and ib as well as a mechanistic explanation for the stereopecificity....
14) 8 Provide the proper IUPAC name for the compounds below complete sentences, explain your choice 45) 6 Cirele the stronger base in the pair below. Using structures and 1-2 46) 14 Provide a detailed, stepwise mechanism for the following rea ction for the major produet AICI, 47) 14 From the following spectrosopic data, provide a structure. Clearly show/calculate/indicate: 1) the elements of unsaturation 2) major peaks/stretches in the IR spectrum 3) the total number of different types of carbons,...
Which of the following compounds can have cis and trans isomers? 2-Methyl-2-butene Propene 0 1-Butene 1,2-Dichloro-1-Bu What is the correct molecular formula of 2,4-Diethyltouleno OCHA 0 C₂ H₂2 G H C:oH20 18 Which of the following compounds can have cis and trans isomers? 1-Butene 2-Methyl-2-butene 1,2-Dichloro-1-Butene Propene CH3CHBr2 is obtained from O Reaction of ethyne with one mole of HBr O Reaction of ethyne with one mole of Br2 Reaction of ethyne with two moles of Br2 Reaction of ethyne...
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