Question

Please show all steps taken (prefer typed solution)O ELECTROCHEMISTRY Picking a reduction or oxidation that will make a galvanic cell work OOOO Yeny v A certain half-reaction h

Half-Reaction E

°

(V)
Ag+ (aq) + e → Ag (s)   0.7996
Al3+ (aq) + 3e → Al (s) −1.676
Au+ (aq) + e → Au (s)   1.692
Au3+ (aq) + 3e → Au (s)   1.498
Ba2+ (aq) + 2e → Ba (s) −2.912
Br2 (l) + 2e → 2Br (aq)   1.066
Ca2+ (aq) + 2e → Ca (s) −2.868
Cl2 (g) + 2e → 2Cl (aq)   1.35827
Co2+ (aq) + 2e → Co (s) −0.28
Co3+ (aq) + e → Co2+ (aq)   1.92
Cr2+ (aq) + 2e → Cr (s) −0.913
Cr3+ (aq) + 3e → Cr (s) −0.744
Cr3+ (aq) + e → Cr2+ (aq) −0.407
CrO42− (aq) + 4H2O (l) + 3e → Cr(OH)3 (s) + 5OH (aq) −0.13
Cu2+ (aq) + 2e → Cu (s)   0.3419
Cu2+ (aq) + e → Cu+ (aq)   0.153
Cu+ (aq) + e → Cu (s)   0.521
F2 (g) + 2e → 2F (aq)   2.866
Fe2+ (aq) + 2e → Fe (s) −0.447
Fe3+ (aq) + e → Fe2+ (aq)   0.771
Fe3+ (aq) + 3e → Fe (s) −0.037
2H+ (aq) + 2e → H2 (g)   0.000
2H2O (l) + 2e → H2 (g) + 2OH (aq) −0.8277
H2O2 (aq) + 2H+ (aq) + 2e → 2H2O (l)   1.776
I2 (s) + 2e → 2I (aq)   0.5355
2IO3 (aq) + 12H+ (aq) + 10e → I2 (s) + 6H2O (l)   1.195
Mg2+ (aq) + 2e → Mg (s) −2.372
Mn2+ (aq) + 2e → Mn (s) −1.185
MnO2 (s) + 4H+ (aq) + 2e → Mn2+ (aq) + 2H2O (l)   1.224
MnO4 (aq) + 8H+ (aq) + 5e → Mn2+ (aq) + 4H2O (l)   1.507
MnO4 (aq) + 2H2O (l) + 3e → MnO2 (s) + 4OH (aq)   0.595
HNO2 (aq) + H+ (aq) + e → NO (g) + H2O (l)   0.983
N2 (g) + 4H2O (l) + 4e → 4OH (aq) + N2H4 (aq) −1.16
NO3 (aq) + 4H+ (aq) + 3e → NO (g) + 2H2O (l)   0.957
Na+ (aq) + e → Na (s) −2.71
Ni2+ (aq) + 2e → Ni (s) −0.257
O2 (g) + 4H+ (aq) + 4e → 2H2O (l)   1.229
O2 (g) + 2H2O (l) + 4e → 4OH (aq)   0.401
O2 (g) + 2H+ (aq) + 2e → H2O2 (aq)   0.695
Pb2+ (aq) + 2e → Pb (s) −0.1262
PbSO4 (s) + H+ (aq) + 2e → Pb (s) + HSO4 (aq) −0.3588
HSO4 (aq) + 3H+ (aq) + 2e → H2SO3 (aq) + H2O (l)   0.172
Sc3+ (aq) + 3e → Sc (s) −2.077
Sn2+ (aq) + 2e → Sn (s) −0.1375
Sn4+ (aq) + 2e → Sn2+ (aq)   0.151
VO2+ (aq) + 2H+ (aq) + e → VO2+ (aq) + H2O (l)   0.991
Zn2+ (aq) + 2e → Zn (s) −0.7618
0 0
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Answer #1

E0cell = E0cathode - E0anode

given cell required volts E0cell = +0.80 V, and E0anode = -0.35 V

E0cathode = E0cell + E0anode = +0.80 V + (-0.35 V) = +0.45 V

E0cathode = +0.45 V

So at least a minimum of +0.45 V must be supplied by cathode to achieve 0.80 V, and there is no maximum limit since they asked us at least 0.80 V should be supplied.

we can use any reaction that has minimum +0.45 V

O ELECTROCHEMISTRY Picking a reduction or oxidation that will make a galvanic cell work OOOO Yeny v A certain half-reaction h

Hope this helped you!

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