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2. Note that the product amine salts are not enantiomers; they are diastereomers. In this experiment...
2. Note that the product amine salts are not enantiomers; they are diastereomers. In this experiment...
2. Note that the product amine salts are not enantiomers; they are diastereomers. In this experiment the (R)-aminium- (S)-ma late diastereomeric salt preferentially crystallized as the less soluble crystals that are easily isolated by vacuum filtration. Where are the (S)-aminium-(S)-malate diastereomers (more soluble crystals) and how could you obtain them from the mixture of diastereomeric salts? What would be the principal problem encountered in doing so?
ootical for pure substance is +40 1. As the new chemist working at "Drugs Us", you...
ootical for pure substance is +40
1. As the new chemist working at "Drugs Us", you are given the task of resolving racemic phenylethyl- amine into its individual enantiomers using (S)-malic acid as resolving agent. After you carried out the resolution, you labeled the products you isolated "Sample A" and "Sample B. You subjected both samples to polarimetry ( = 589 nm (sodium D-line), 1-dm cell) and obtained the following results. Sample A: 1.00 g dissolved in 10.0 mL methanol...
3. Instead of trying to isolate the more soluble (S)-aminium-(S)-malate diastereomers from the mixture of diastereomeric...
3. Instead of trying to isolate the more soluble (S)-aminium-(S)-malate diastereomers from the mixture of diastereomeric salts, what would be a better way of ensuring that the (S)-(-)-amine diastereomeric salt crystallizes preferentially as the less soluble crystals? Hint: What is the enantiomer of the (R)-aminium-(S)-malate diastereomer and how could it be formed?
Please help with pre-lab questions. Pre-Lab Questions: 1. A sample of 2-butanol has a specific rotation...
Please help with pre-lab questions.
Pre-Lab Questions: 1. A sample of 2-butanol has a specific rotation of +3.25. Determine the optical purity (%ee) and percent composition of this sample (see Mohrig section 17.4). The specific rotation of pure (+)-2-butanol is +13.0°. 2. The equation for the formation of the diastereomeric salts is shown in the background information (performed in Part A of the procedure). Write this chemical equation in your notebook, then ALSO write a balanced equation for the formation...
Extraction of solids: Experiment outlined below Draw a “roadmap” of the experiment, containing chemical structures and...
Extraction of solids: Experiment outlined below
Draw a “roadmap” of the experiment, containing chemical
structures and “layers” (organic and aqueous). This should contain
the individual reactions occurring in each step, and show which
layer the various components are present. Make sure you think about
whether the acetaminophen, caffeine and aspirin are neutral,
protonated or deprotonated.
Preliminary separation obtain a sample (1.0g) of the mixture. weigh the sample and record it. this sample should consist of a 2:1:1 mixture (by mass)...
Experiment 12: Synthesis of Benzoic Acid pre-lab (4 pts) 1 (2 pts) Refer to the introduction...
Experiment 12: Synthesis of Benzoic Acid pre-lab (4 pts) 1 (2 pts) Refer to the introduction on the general process of hydrolysis of nitriles to carboxylic acids. Starting with benzonitrile (shown below), show how it is converted to benzoic acid under basic conditions. N 2) (2 pts) The reaction for the synthesis of benzoic acid via benzonitrile hydrolysis is shown below: 1) NaOH, HO YOH + NaCl 2) HCI, H,0 Benzonitrile Density = 1.0 g/mL MM = 103.04 g/mol Benzoic...
help with identifiying each unknown in extraction and washing experiment. the ir spectra are given below,...
help with identifiying each unknown in extraction and washing
experiment. the ir spectra are given below, along with data, and
the lab sheet is attached.
Neutral Solid Primary amine (Aniline) 3403cm - NE presence Transmittance 60 3258cm 1 streren NOUD Streich 50 Ctretcher strator NH2 aromatto 11 NO2 aring 2-nitroaniline K LILI 3600 3200 2800 2400 2000 1800 1600 Wavenumber cm-1 1400 1200 1000 800 600 Basic Solid primary amine Transmittance I NH2 Stretch p-acetvianiline 70 60 CS HG NO...
Separating a Mixture, Recrystallization, pre-lab assignment could you also explain why you chose that substance for...
Separating a Mixture, Recrystallization, pre-lab
assignment
could you also explain why you chose that substance for the empty
spaces and question marks
EXPERIMENT 4 Pre-Lab Assignment Separating a Mixture, Recrystalliration Name Date 1. Complete the following flowchart which shows how to separate a mixture of sand, sodium chloride and acetanilide. Notice that after a separation process (a down arrow) the filtered solids are shown on the left and the filtrate (the liquid) is shown on the right. The terminal step...
Experiment 7 Preparation of Alum PURPOSE oF EXPERIMENT: Prepare KAI(So,)2 12H20, an aluminum alum...
CHEM 101 LAB 7 PRELAB QUESTIONS B C AND D
Experiment 7 Preparation of Alum PURPOSE oF EXPERIMENT: Prepare KAI(So,)2 12H20, an aluminum alum, from aluminum metal. (Note: ExPERIMENT 8 describes the gravimetric analysis of the sulfate content in alum.) Alums have the general formula MM(So) 12HO, where M* is commonly Na". K', Tl., NH,., or Ag, and Mt''is A广, Fe". Cr". Ti". or Co. . Samples of these compounds have a variety of uses in our everyday lives. Sodium...
Construct a flow chart describing the seperation of the mixture and the isolation of each compound...
Construct a flow chart describing the seperation of the
mixture and the isolation of each compound in this experiment. (Lab
steps/procedures includes for reference)
4. Construct a flow chart describing the separation of the mixture and the isolation of each compound in this experiment. A commonly used method of separating a mixture of organic compounds is known as liquid-liquid extraction. Most reactions of organic compounds require extraction at some stage of product purification. In this experiment you will use extraction...
2. Note that the product amine salts are not enantiomers; they are diastereomers. In this experiment the (R)-aminium- (S)-ma late diastereomeric salt preferentially crystallized as the less soluble crystals that are easily isolated by vacuum filtration. Where are the (S)-aminium-(S)-malate diastereomers (more soluble crystals) and how could you obtain them from the mixture of diastereomeric salts? What would be the principal problem encountered in doing so?
ootical for pure substance is +40
1. As the new chemist working at "Drugs Us", you are given the task of resolving racemic phenylethyl- amine into its individual enantiomers using (S)-malic acid as resolving agent. After you carried out the resolution, you labeled the products you isolated "Sample A" and "Sample B. You subjected both samples to polarimetry ( = 589 nm (sodium D-line), 1-dm cell) and obtained the following results. Sample A: 1.00 g dissolved in 10.0 mL methanol...
3. Instead of trying to isolate the more soluble (S)-aminium-(S)-malate diastereomers from the mixture of diastereomeric salts, what would be a better way of ensuring that the (S)-(-)-amine diastereomeric salt crystallizes preferentially as the less soluble crystals? Hint: What is the enantiomer of the (R)-aminium-(S)-malate diastereomer and how could it be formed?
Please help with pre-lab questions.
Pre-Lab Questions: 1. A sample of 2-butanol has a specific rotation of +3.25. Determine the optical purity (%ee) and percent composition of this sample (see Mohrig section 17.4). The specific rotation of pure (+)-2-butanol is +13.0°. 2. The equation for the formation of the diastereomeric salts is shown in the background information (performed in Part A of the procedure). Write this chemical equation in your notebook, then ALSO write a balanced equation for the formation...
Extraction of solids: Experiment outlined below
Draw a “roadmap” of the experiment, containing chemical
structures and “layers” (organic and aqueous). This should contain
the individual reactions occurring in each step, and show which
layer the various components are present. Make sure you think about
whether the acetaminophen, caffeine and aspirin are neutral,
protonated or deprotonated.
Preliminary separation obtain a sample (1.0g) of the mixture. weigh the sample and record it. this sample should consist of a 2:1:1 mixture (by mass)...
Experiment 12: Synthesis of Benzoic Acid pre-lab (4 pts) 1 (2 pts) Refer to the introduction on the general process of hydrolysis of nitriles to carboxylic acids. Starting with benzonitrile (shown below), show how it is converted to benzoic acid under basic conditions. N 2) (2 pts) The reaction for the synthesis of benzoic acid via benzonitrile hydrolysis is shown below: 1) NaOH, HO YOH + NaCl 2) HCI, H,0 Benzonitrile Density = 1.0 g/mL MM = 103.04 g/mol Benzoic...
help with identifiying each unknown in extraction and washing
experiment. the ir spectra are given below, along with data, and
the lab sheet is attached.
Neutral Solid Primary amine (Aniline) 3403cm - NE presence Transmittance 60 3258cm 1 streren NOUD Streich 50 Ctretcher strator NH2 aromatto 11 NO2 aring 2-nitroaniline K LILI 3600 3200 2800 2400 2000 1800 1600 Wavenumber cm-1 1400 1200 1000 800 600 Basic Solid primary amine Transmittance I NH2 Stretch p-acetvianiline 70 60 CS HG NO...
Separating a Mixture, Recrystallization, pre-lab
assignment
could you also explain why you chose that substance for the empty
spaces and question marks
EXPERIMENT 4 Pre-Lab Assignment Separating a Mixture, Recrystalliration Name Date 1. Complete the following flowchart which shows how to separate a mixture of sand, sodium chloride and acetanilide. Notice that after a separation process (a down arrow) the filtered solids are shown on the left and the filtrate (the liquid) is shown on the right. The terminal step...
CHEM 101 LAB 7 PRELAB QUESTIONS B C AND D
Experiment 7 Preparation of Alum PURPOSE oF EXPERIMENT: Prepare KAI(So,)2 12H20, an aluminum alum, from aluminum metal. (Note: ExPERIMENT 8 describes the gravimetric analysis of the sulfate content in alum.) Alums have the general formula MM(So) 12HO, where M* is commonly Na". K', Tl., NH,., or Ag, and Mt''is A广, Fe". Cr". Ti". or Co. . Samples of these compounds have a variety of uses in our everyday lives. Sodium...
Construct a flow chart describing the seperation of the
mixture and the isolation of each compound in this experiment. (Lab
steps/procedures includes for reference)
4. Construct a flow chart describing the separation of the mixture and the isolation of each compound in this experiment. A commonly used method of separating a mixture of organic compounds is known as liquid-liquid extraction. Most reactions of organic compounds require extraction at some stage of product purification. In this experiment you will use extraction...
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