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Students sometimes use HNO3 (aq) instead of H2SO4 (aq) in reaction E, Step 4, assuming that...

Students sometimes use HNO3 (aq) instead of H2SO4 (aq) in reaction E, Step 4, assuming that both strong acids will accomplish the same purpose. Briefly describe the consequences of this error.

Reaction E: magnesium metal acts as a reducing agent to convert the aqueous copper (II) sulfate to pure (reduced) copper metal, Cu:

CuSO4 (aq) + Mg(s) = Cu(s) + MgSO4 (aq)

In a competing reaction, magnesium also reduces sulfuric acid, with formation of hydrogen gas and aqueous magnesium sulfate:

Mg(s) + H2SO4 (aq) = H2 (g) + MgSO4 (aq)

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Answer #1

Answer: HNO3 acts both as oxidising agent as well as strong acid. Thus, during the reaction of Mg with HNO3 , the H2 gas is not liberated because nitric acid oxidises the hydrogen gas to H2O and itself gets reduced.

4 Mg(aq) + 10 HNO3(aq) → 4 Mg(NO3)2 (aq) + N2O + 5H2O

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