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Predict the products.
16. K2Cr207 (excess) H2SO4, H2O HO 1. Phli, Et20 2. HCI, H20 3....
K2Cr207 (excess) H2SO4, H2O HO OH u. 1. PhLi, Et20 2. HCI, H2O 3. SOCl2, Etz 4. NaOAC 1. Mg (1 eq), Et20 Br 2. i (1 eq)...
K2Cr207 (excess) H2SO4, H2O HO OH u. 1. PhLi, Et20 2. HCI, H2O 3. SOCl2, Etz 4. NaOAC 1. Mg (1 eq), Et20 Br 2. i (1 eq) -CHO 3. HCI, H20 1. NaBH4, MeOH, 0°C 2. PBr3, THE 3. LiAID4, THE 4. HCI, H2O x. 1. SOCI, NEtz, THE CHO 2. 2 eq Li, hexane 3. HCI, H2O hint: multiple steps 1. LiAIHA, THE 2. HCI, H20 3. PBrz, THE a1. 1. PCC, DCM OH 2. Mg, Et20 3....
K2Cr2O, (excess) HASOHO 1. Phli, Et 2. HCI, H2O 3. SOCI, EIN 4. NaOAC 1. Mg...
K2Cr2O, (excess) HASOHO 1. Phli, Et 2. HCI, H2O 3. SOCI, EIN 4. NaOAC 1. Mg (1 eg). Et, 2. i (19) -CHO 3. HCI, H20 1. NaBH4, MeOH, 0°C 2. PB.. THE 3. LIAID, THE 4. HCI, H20 1. SOCI, NE. THE 2. 2 eq Li, hexane 3. HCI, H20 Pintuicio sops 1. LiAlH. THE 2. HCI, H2O 3. PB. THE 1. PCC, DCM OH 2. Mg, Et20 3.HCI, H20 1. MsCl, pyr 2. KO'Bu, 'BuOH
predict the product (or reactants) 1. Mg (1 eq). Et20 2. (1 eq) -CHO 3. HCI,...
predict the product (or reactants)
1. Mg (1 eq). Et20 2. (1 eq) -CHO 3. HCI, H2O 1. NaBH4, MeOH, 0°C 2. PBrz. THE 3. LIAID, THE 4. HCI, H20 1. SOCI, NEt3, THF 2. 2 eq Li, hexane CHO 3, HCl, H2O hint multiple steps CH 1. LiAIH, THE 2. HCI, H2O 3. PBr3, THF OH 1. PCC, DCM 2. Mg, Et20 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, 'BuOH
Predict the product(s) and reagent(s) or if there is no reaction write NR. OH K2Cr207 (excess)...
Predict the product(s) and reagent(s) or if there is no reaction
write NR.
OH K2Cr207 (excess) H2SO4, H20 "ОН 1. PhLi, Et20 2. HCI, HO 3. SOCl2, Et3N 4. NaOAC 1. Mg (1 eq), Et20 < Br 2. (1 eq) CHO 3. HCI, H2O MsCI LDA ОН pyridine 1. Nah 2. Br
1. SOCI, NEt3, THE 2. 2 eq Li, hexane 3. HCI, H2O CHO Br hint: multiple steps B TH 1. LIAIH, THE 2. HCI, H2O 3. PBr...
1. SOCI, NEt3, THE 2. 2 eq Li, hexane 3. HCI, H2O CHO Br hint: multiple steps B TH 1. LIAIH, THE 2. HCI, H2O 3. PBr3, THE CN OH 1. PCC, DCM 2. Mg, Et O 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, 'BuOH
1. Predict the product(s) (or no reaction) and reagent(s). (31 pts; no partial point) OTE hint:...
1. Predict the product(s) (or no reaction) and reagent(s). (31
pts; no partial point)
OTE hint: multiple steps 1. LiAlH4, THE 2. HCI, H2O 3. PBr3, THE CN a1. LOH 1. PCC, DCM 2. Mg, Et20 3. HCI, H20 1. MSCI, pyr 2. KO'Bu, BuOH
predict the reactants and products to complete reaction mechanism OTE oprer Br hint: multiple steps 1....
predict the reactants and products to complete reaction
mechanism
OTE oprer Br hint: multiple steps 1. LiAIH4, THE 2. HCI, H2O 3. PBr3, THE 3 D LO a1. 1. PCC, DCM 2. Mg, Et20 3. HCI, H20 1. MSCI, pyr 2. KO'Bu, 'BuOH uw
Predict the product(s) and reagent(s) or if there is no reaction write NR. 041 for 1....
Predict the product(s) and reagent(s) or if there is no reaction
write NR.
041 for 1. NaBH4, MeOH, 0°C 2. PBr3, THE 3. LiAlD4, THE 4. HCI, H20 1. SOCl2, NEt3, THE CHO 2. 2 eq Li, hexane 3. HCI, H2O OTE hint: multiple steps 1. LIAIH4, THE 2. HCI, H2O 3. PBr3, THE CN OH 1. PCC, DCM 2. Mg, Et O 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, BuOH
OH r. Он reagent(s) Br OEt S. reagent(s) Br Он K2Cr2O7 (excess) H2SO4, H20 Он но...
OH r. Он reagent(s) Br OEt S. reagent(s) Br Он K2Cr2O7 (excess) H2SO4, H20 Он но 1. PhLi, Et O 2. HCI, H2O 3. SOCI2, EtN 4. NaOAc u. н 1. Mg (1 eq), Et2O V. Br 2. (1 eq) -сно 3. HCI, Н,О W. 1. NaBH,, MeOН, 0° С 2. PBra THF 3. LIAID4, THF 4. HCI, H20
1. Predict the product(s) (or no reaction) and reagent(s). (31 pts; no partial point) t ОН...
1. Predict the product(s) (or no reaction) and reagent(s). (31
pts; no partial point)
t ОН КаСr2О7 (ехсess) Н2SO4, H2O ОН НО Д 1. PhLi, Et2O 2. HСI, H2О 3. SOCI2, EtgN 4. NaOAc u. H 1. Mg (1 eq), Et20 V. Br 2. (1 еq) СНО 3. НС, Н2О W. 1. NaBH4, MeOН, 0° С 2. PBrз, THF 3. LIAID4, THF 4. HС, H20 ОН Х. 1. SOCI2, NEt3, THF 2. 2 eq Li, hexane 3. HСІ, Н2О СНО
K2Cr207 (excess) H2SO4, H2O HO OH u. 1. PhLi, Et20 2. HCI, H2O 3. SOCl2, Etz 4. NaOAC 1. Mg (1 eq), Et20 Br 2. i (1 eq) -CHO 3. HCI, H20 1. NaBH4, MeOH, 0°C 2. PBr3, THE 3. LiAID4, THE 4. HCI, H2O x. 1. SOCI, NEtz, THE CHO 2. 2 eq Li, hexane 3. HCI, H2O hint: multiple steps 1. LiAIHA, THE 2. HCI, H20 3. PBrz, THE a1. 1. PCC, DCM OH 2. Mg, Et20 3....
K2Cr2O, (excess) HASOHO 1. Phli, Et 2. HCI, H2O 3. SOCI, EIN 4. NaOAC 1. Mg (1 eg). Et, 2. i (19) -CHO 3. HCI, H20 1. NaBH4, MeOH, 0°C 2. PB.. THE 3. LIAID, THE 4. HCI, H20 1. SOCI, NE. THE 2. 2 eq Li, hexane 3. HCI, H20 Pintuicio sops 1. LiAlH. THE 2. HCI, H2O 3. PB. THE 1. PCC, DCM OH 2. Mg, Et20 3.HCI, H20 1. MsCl, pyr 2. KO'Bu, 'BuOH
predict the product (or reactants)
1. Mg (1 eq). Et20 2. (1 eq) -CHO 3. HCI, H2O 1. NaBH4, MeOH, 0°C 2. PBrz. THE 3. LIAID, THE 4. HCI, H20 1. SOCI, NEt3, THF 2. 2 eq Li, hexane CHO 3, HCl, H2O hint multiple steps CH 1. LiAIH, THE 2. HCI, H2O 3. PBr3, THF OH 1. PCC, DCM 2. Mg, Et20 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, 'BuOH
Predict the product(s) and reagent(s) or if there is no reaction
write NR.
OH K2Cr207 (excess) H2SO4, H20 "ОН 1. PhLi, Et20 2. HCI, HO 3. SOCl2, Et3N 4. NaOAC 1. Mg (1 eq), Et20 < Br 2. (1 eq) CHO 3. HCI, H2O MsCI LDA ОН pyridine 1. Nah 2. Br
1. SOCI, NEt3, THE 2. 2 eq Li, hexane 3. HCI, H2O CHO Br hint: multiple steps B TH 1. LIAIH, THE 2. HCI, H2O 3. PBr3, THE CN OH 1. PCC, DCM 2. Mg, Et O 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, 'BuOH
1. Predict the product(s) (or no reaction) and reagent(s). (31
pts; no partial point)
OTE hint: multiple steps 1. LiAlH4, THE 2. HCI, H2O 3. PBr3, THE CN a1. LOH 1. PCC, DCM 2. Mg, Et20 3. HCI, H20 1. MSCI, pyr 2. KO'Bu, BuOH
predict the reactants and products to complete reaction
mechanism
OTE oprer Br hint: multiple steps 1. LiAIH4, THE 2. HCI, H2O 3. PBr3, THE 3 D LO a1. 1. PCC, DCM 2. Mg, Et20 3. HCI, H20 1. MSCI, pyr 2. KO'Bu, 'BuOH uw
Predict the product(s) and reagent(s) or if there is no reaction
write NR.
041 for 1. NaBH4, MeOH, 0°C 2. PBr3, THE 3. LiAlD4, THE 4. HCI, H20 1. SOCl2, NEt3, THE CHO 2. 2 eq Li, hexane 3. HCI, H2O OTE hint: multiple steps 1. LIAIH4, THE 2. HCI, H2O 3. PBr3, THE CN OH 1. PCC, DCM 2. Mg, Et O 3. HCI, H2O 1. MSCI, pyr 2. KO'Bu, BuOH
OH r. Он reagent(s) Br OEt S. reagent(s) Br Он K2Cr2O7 (excess) H2SO4, H20 Он но 1. PhLi, Et O 2. HCI, H2O 3. SOCI2, EtN 4. NaOAc u. н 1. Mg (1 eq), Et2O V. Br 2. (1 eq) -сно 3. HCI, Н,О W. 1. NaBH,, MeOН, 0° С 2. PBra THF 3. LIAID4, THF 4. HCI, H20
1. Predict the product(s) (or no reaction) and reagent(s). (31
pts; no partial point)
t ОН КаСr2О7 (ехсess) Н2SO4, H2O ОН НО Д 1. PhLi, Et2O 2. HСI, H2О 3. SOCI2, EtgN 4. NaOAc u. H 1. Mg (1 eq), Et20 V. Br 2. (1 еq) СНО 3. НС, Н2О W. 1. NaBH4, MeOН, 0° С 2. PBrз, THF 3. LIAID4, THF 4. HС, H20 ОН Х. 1. SOCI2, NEt3, THF 2. 2 eq Li, hexane 3. HСІ, Н2О СНО
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