Homework Answers
1
st step is polarization of Chlorine molecule, then attack of
elctrophile and abstracts proton by conjugate base to aromatization
forms chlorobenzene.
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3. (15 points each) Predict the products and present a detailed mechanism for the following reactions....
AICI: 3. (15 points each) Predict the products and present a detailed mechanism for the following...
AICI: 3. (15 points each) Predict the products and present a detailed mechanism for the following reactions. If an intermediate is stabilized by resonance, draw all resonance structures. Show all lone pair electrons and label any charged atoms.
AICI 3. (15 points each) Predict the products and present a detailed mechanism for the following...
AICI 3. (15 points each) Predict the products and present a detailed mechanism for the following reactions. If an intermediate is stabilized by resonance, draw all resonance structures. Show all lone pair electrons and label any charged atoms.
1) Consider the acid-base reaction below. A) Predict the products and show the arrow.pushing mechanism and...
1) Consider the acid-base reaction below. A) Predict the products and show the arrow.pushing mechanism and all of the resonance structures for any resonance-stabilized products. B) Estimate K for this reaction. + Na o
1) Predict the Products: Using line drawings with proper use of dashed wedge and solid wedge...
1) Predict the Products: Using line drawings with proper use of
dashed wedge and solid wedge notation where necessary, draw the
major organic products of the following reactions in the boxes
provided. If no reaction occurs write “no reaction” or “N.R.” in
the box. Include stereochemistry in your answers where appropriate.
If a product is racemic draw both enantiomers or write “racemic”
next to the structure. Assume all reagents written above and below
the arrows are present in excess unless...
6. Predict the product and draw a mechanism for the reactions below. You MUST include the...
6. Predict the product and draw a mechanism for the reactions below. You MUST include the mechanism for the formation of the electrophile. Be sure to show arrows for every bond change and draw the resonance structures of the carbocation intermediate. AICI: SO3 H2SO4
Show lone pairs on all appropriate atoms and the proper flow of electrons. (1) Mechanism #1:...
Show lone pairs on all appropriate atoms and the proper flow of electrons. (1) Mechanism #1: • Predict the products of the following reaction under different temperature conditions. • Show the mechanism for how the two products are formed at different temperatures (include resonance structures if appropriate). • Label the kinetic product and the thermodynamic product. (5 points) -80 °C + HBr 40 °C (2) Predict the product and show the complete mechanism for the following reaction. • Make sure...
Question 3. Predict the major products of the reactions below. Draw the full mechanism for the...
Question 3. Predict the major products of the reactions below. Draw the full mechanism for the reactions, using appropriate arrows to indicate electron movement and the full structures of any intermediate(s). Use the mechanism of the reaction to provide a rationale for why the major product formed. OM (1 equivalent) ansole Bry Febr (1 culle brambenzone Fer (1 equivalent Priloromethylbenzene (9 marks) Question 4. Predict the major product from the treatment of 2,5-dibromopyridine with ammonia. Draw the full mechanism for...
1.(10 points) Consider the reactive intermediate below: A) In the space below draw all significantly contributing...
1.(10 points) Consider the reactive intermediate below: A) In the space below draw all significantly contributing resonance structures (including lone pairs). Use curved arrows to indicate the flow of electrons between the resonance structures. b) In the resonance structures you have drawn above, predict which one will be the most stabilized resonance contributor. Discuss briefly (1 sentence) why you chose this structure to be the most stable contributor to the resonance hybrid.
Provide detailed mechanisms for each of the following reactions. Be certain to use arrow pushing (electron...
Provide detailed mechanisms for each of the following reactions. Be certain to use arrow pushing (electron pushing) and to draw out all intermediates. If an intermediate is resonance stabilized, draw the most stable resonance contributor. H2SO4 a) heat CH3 нс 1 HI Ное heat c)
3. (24 pts.) give a reasonable mechanism for each of the following reactions.
give a reasonable mechanism for each of the following reactions. Be sure to use electron pushing (arrow pushing) and to include all intermediates. In cases where an intermediate is resonance stabilized, dry the most stable resonance contributor.
AICI: 3. (15 points each) Predict the products and present a detailed mechanism for the following reactions. If an intermediate is stabilized by resonance, draw all resonance structures. Show all lone pair electrons and label any charged atoms.
AICI 3. (15 points each) Predict the products and present a detailed mechanism for the following reactions. If an intermediate is stabilized by resonance, draw all resonance structures. Show all lone pair electrons and label any charged atoms.
1) Consider the acid-base reaction below. A) Predict the products and show the arrow.pushing mechanism and all of the resonance structures for any resonance-stabilized products. B) Estimate K for this reaction. + Na o
1) Predict the Products: Using line drawings with proper use of
dashed wedge and solid wedge notation where necessary, draw the
major organic products of the following reactions in the boxes
provided. If no reaction occurs write “no reaction” or “N.R.” in
the box. Include stereochemistry in your answers where appropriate.
If a product is racemic draw both enantiomers or write “racemic”
next to the structure. Assume all reagents written above and below
the arrows are present in excess unless...
6. Predict the product and draw a mechanism for the reactions below. You MUST include the mechanism for the formation of the electrophile. Be sure to show arrows for every bond change and draw the resonance structures of the carbocation intermediate. AICI: SO3 H2SO4
Show lone pairs on all appropriate atoms and the proper flow of electrons. (1) Mechanism #1: • Predict the products of the following reaction under different temperature conditions. • Show the mechanism for how the two products are formed at different temperatures (include resonance structures if appropriate). • Label the kinetic product and the thermodynamic product. (5 points) -80 °C + HBr 40 °C (2) Predict the product and show the complete mechanism for the following reaction. • Make sure...
Question 3. Predict the major products of the reactions below. Draw the full mechanism for the reactions, using appropriate arrows to indicate electron movement and the full structures of any intermediate(s). Use the mechanism of the reaction to provide a rationale for why the major product formed. OM (1 equivalent) ansole Bry Febr (1 culle brambenzone Fer (1 equivalent Priloromethylbenzene (9 marks) Question 4. Predict the major product from the treatment of 2,5-dibromopyridine with ammonia. Draw the full mechanism for...
1.(10 points) Consider the reactive intermediate below: A) In the space below draw all significantly contributing resonance structures (including lone pairs). Use curved arrows to indicate the flow of electrons between the resonance structures. b) In the resonance structures you have drawn above, predict which one will be the most stabilized resonance contributor. Discuss briefly (1 sentence) why you chose this structure to be the most stable contributor to the resonance hybrid.
Provide detailed mechanisms for each of the following reactions. Be certain to use arrow pushing (electron pushing) and to draw out all intermediates. If an intermediate is resonance stabilized, draw the most stable resonance contributor. H2SO4 a) heat CH3 нс 1 HI Ное heat c)
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