6. Rank these carbon radicals from most stable to least stable: H C H Н—с—н (X)...
order the following carbon radicals from most stable to least stable (1&2) 1. Order the following carbon radicals from most stable to least stable. 5 3 2 2. Complete the following reaction scheme. "What goes over the arrow?" Write your answers in the spaces provided below. MgBr Br E Br ОН MgCl CI F G В Н Br Reagents required for the above reactions: F. А. G. В. Н. С. I. D. J. E. (
3) Which of the following compounds is chiral? A) H Н-С-н н B) H HO C-OH Н C) CH3 HO-C-H Cl D) Br Н-С-ОН н E) C Br- C-C Br 4) In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written A) on the left of the top chiral carbon B) on the right of the top chiral carbon C) on the left of the middle chiral carbon D) on...
2) Order the following alkenes from most stable to least stable Нас Нас с-сн, н,с Hас +C- Нас н CHs -CH3 H Hе most stable least stable (a) I (b) I (c) I ll (d) 7) Order the following C-H bonds from strongest to weakest. strongest weakest (a) (b) (c) II (d) 8) Which of the following is represents the lowest energy transition state for the addition of BH, to 2-methyl-1-propene? quCH «сHs нСи Нас (b) (a) Нив--н H H...
NA afte. 9 Select the most stable conformation for trans-1-tert-butyl-3-methylcyclohexane. н D A 10. Which of the following compounds are optically active [will rotate plane polarized light (is chiral)]? CIL CI CI CI C/. CI A CI CI В D С 11. Rank absorption of the indicated bonds in decreasing (highest to lowest) wavenumber. II н x III a) III> II>I b) I> II III OH c) II>I> IlI d) III I> II но, но—н 12. How many stereocenters are...
Question 6 Is the molecule below a carbohydrate? HỌ -C-H. н—с-он CH OH
Rank these radicals from least to most stable. O A<B<C O A<C<B OB<A<C OB<C<A Ò C<A<B OC <B<A
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers and meso compounds. II) Assign the absolute configuration of chiral carbons in each molecule OCH3 HO+Br HS+CN H2N-CH3 HOSH Он HO+CH3 н OCH3 Сн, ососна Br +D HOCH HC-BrHN+Br CH 8. For the following compounds, assign the absolute configuration for those with chiral carbons and identify those that are NOT enantiomers HO C-C-OHY -CCIN 13CH3 HAN CH3 CH3 осі H-CH3 H2N+CH H O+COOH...
A. aldehyde B. ketones C. carboxylic acids D. esters 7, How many stereoisomers of 2,4-pentanediol are possible? но он В. З A. 2 C. 4 D. 6 8.Which one of the following is a diastereomer of (2R, 3R)-2,3-dibromopentane? A. (2S,3S)-2,3-dibromopentane C.R-1,2-dibromopentane B. (2S,3R)-2,3-dibromopentane D. (2R,4R)-2,4-dibromopentane 9. Which one of the following groups has the highest rank as assigned by the Cahn-Ir Prelog system for stereogenic carbons? A. -CH-CH2 B. -CH20H C.-CH-0 D. -CH2SH 10. Which of the following statements are...
s (c) NH2 Rank the molecules shown in Figure 6 from H) most acidic to least acidic (example:dcba . NH2 он Figure 6 ) Which of the following is most stable carbocation? i) methyl i) primary i) secondary iv) tertiany v) Hiv are approximately equal in stability J) Which of the following is not a characteristic of most aromatic compounds like benzene? i) they are cyclic li) they are planar ii) they are resonance stabilized iv) the aikenes of the...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...