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FALL 2019 QUIZNIO 1 Draw the MAJOR organic products of each reaction and indicate stereochemistry where...
Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You...
Give a reasonable synthesis for
each of the following compounds from the indicated starting
materials. You may use any other organic or inorganic reagents you
wish unless otherwise indicated. The desired product for each
reaction you propose must be the one of the predominant products.
Give the reactants, conditions (where appropriate) and products of
each synthetic step. If equal mixtures are anticipated (i.e. ortho
/ para products) then indicate where separations are needed. NO
MECHANISMS! [6 points
2. Give a...
9.RETROSYNTHETIC ANALYSIS Give a reasonable synthesis for the following compound from the indicated starting materials. You...
9.RETROSYNTHETIC ANALYSIS Give a reasonable synthesis for the following compound from the indicated starting materials. You may use any other organic reagents or inorganic reagents you wish. The desired product for each reaction must be the MAJOR PRODUCT. Give the reactants, conditions (where appropriate), and products of each synthetic step but NO MECHANISMS. [4 points) OH Use to make HO
Retrosynthetic Analysis 12. Give a reasonable synthesis for each of the following compounds from the indicated...
Retrosynthetic Analysis 12. Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. NO MECHANISMS! [8 points] NH ONH2 Make starting with
7. MECHANISM: Give the complete stepwise mechanism to account for the following observation. Use curved arrows...
7. MECHANISM: Give the complete stepwise mechanism to account for the following observation. Use curved arrows to show FLOW OF ELECTRONS. [9 points H-CI 8.RETROSYNTHETIC ANALYSIS Give a reasonable synthesis for the following compound from the indicated starting materials. You may use any other organic reagents or inorganic reagents you wish. The desired product for each reaction must be the MAJOR PRODUCT. Give the reactants, conditions (where appropriate), and products of each synthetic step but NO MECHANISMS. [6 points] OH...
Synthesis 10. Give a reasonable synthesis for the following compound from the indicated starting material. You...
Synthesis 10. Give a reasonable synthesis for the following compound from the indicated starting material. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. NO MECHANISMS! [6 points) Make med og som en ons starting with SO3H
please explain why the answer is the answer step by step Retrosynthetic Analysis Give a reasonable...
please explain why the answer is the answer step by step
Retrosynthetic Analysis Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. If equal mixtures are anticipated (ie. ortho/para products) then indicate...
Draw the major organic product from reaction of 1-butyne with 2 equiv HCI. • Specify stereochemistry...
Draw the major organic product from reaction of 1-butyne with 2 equiv HCI. • Specify stereochemistry when it is relevant. • In cases where there is more than one answer, just draw one. . Do not draw inorganic by-products • If no reaction occurs, draw the organic starting material. Co @ 7 /1000 [] ChemDoodle
Predicting Products: Draw the structure of the one major organic product of each reaction in the...
Predicting Products: Draw the structure of the one major organic product of each reaction in the boxes provided. Be aware that the products all have the molecular formula C6H100, but oth products are constitutional isomers of one another. Stereochemistry should be shown if applicable. HO. Nah, DMSO Br HO, Nah, DMSO Br An efficient way to prepare asymmetrical ethers was developed by a British scientist, Alexander Williamson. Show what reagents you would use to prepare the following compound via a...
1. (7 points) Draw the major, organic product generated for each of the reactions regiochemistry and...
1. (7 points) Draw the major, organic product generated for each of the reactions regiochemistry and stereochemistry. Be sure to indicate if more than one enantiomer is formed. below. Pay particular attention to the CI dilute H2SO4 KCN C2, H20 (dark) 1. BH3 THF 2. H2O2, KOH 1. NaH 2. allyl chloride (e) Draw the stereoisomer of 2,3-diphenylbut-2-ene that yields meso-2,3-dibromo-2,3-diphenylbutane on reaction with Br2 in the cold, darkness. 2.(2 points) Complete the following synthesis by filing in the missing...
Draw the major organic product from reaction of 1-butyne with 1 equiv Br2 Specify stereochemistry when...
Draw the major organic product from reaction of 1-butyne with 1 equiv Br2 Specify stereochemistry when it is relevant. In cases where there is more than one answer, just draw one. • Do not draw inorganic by-products. • If no reaction occurs, draw the organic starting material. OOO.
Give a reasonable synthesis for
each of the following compounds from the indicated starting
materials. You may use any other organic or inorganic reagents you
wish unless otherwise indicated. The desired product for each
reaction you propose must be the one of the predominant products.
Give the reactants, conditions (where appropriate) and products of
each synthetic step. If equal mixtures are anticipated (i.e. ortho
/ para products) then indicate where separations are needed. NO
MECHANISMS! [6 points
2. Give a...
9.RETROSYNTHETIC ANALYSIS Give a reasonable synthesis for the following compound from the indicated starting materials. You may use any other organic reagents or inorganic reagents you wish. The desired product for each reaction must be the MAJOR PRODUCT. Give the reactants, conditions (where appropriate), and products of each synthetic step but NO MECHANISMS. [4 points) OH Use to make HO
Retrosynthetic Analysis 12. Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. NO MECHANISMS! [8 points] NH ONH2 Make starting with
7. MECHANISM: Give the complete stepwise mechanism to account for the following observation. Use curved arrows to show FLOW OF ELECTRONS. [9 points H-CI 8.RETROSYNTHETIC ANALYSIS Give a reasonable synthesis for the following compound from the indicated starting materials. You may use any other organic reagents or inorganic reagents you wish. The desired product for each reaction must be the MAJOR PRODUCT. Give the reactants, conditions (where appropriate), and products of each synthetic step but NO MECHANISMS. [6 points] OH...
Synthesis 10. Give a reasonable synthesis for the following compound from the indicated starting material. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. NO MECHANISMS! [6 points) Make med og som en ons starting with SO3H
please explain why the answer is the answer step by step
Retrosynthetic Analysis Give a reasonable synthesis for each of the following compounds from the indicated starting materials. You may use any other organic or inorganic reagents you wish unless otherwise indicated. The desired product for each reaction you propose must be the one of the predominant products. Give the reactants, conditions (where appropriate) and products of each synthetic step. If equal mixtures are anticipated (ie. ortho/para products) then indicate...
Draw the major organic product from reaction of 1-butyne with 2 equiv HCI. • Specify stereochemistry when it is relevant. • In cases where there is more than one answer, just draw one. . Do not draw inorganic by-products • If no reaction occurs, draw the organic starting material. Co @ 7 /1000 [] ChemDoodle
Predicting Products: Draw the structure of the one major organic product of each reaction in the boxes provided. Be aware that the products all have the molecular formula C6H100, but oth products are constitutional isomers of one another. Stereochemistry should be shown if applicable. HO. Nah, DMSO Br HO, Nah, DMSO Br An efficient way to prepare asymmetrical ethers was developed by a British scientist, Alexander Williamson. Show what reagents you would use to prepare the following compound via a...
1. (7 points) Draw the major, organic product generated for each of the reactions regiochemistry and stereochemistry. Be sure to indicate if more than one enantiomer is formed. below. Pay particular attention to the CI dilute H2SO4 KCN C2, H20 (dark) 1. BH3 THF 2. H2O2, KOH 1. NaH 2. allyl chloride (e) Draw the stereoisomer of 2,3-diphenylbut-2-ene that yields meso-2,3-dibromo-2,3-diphenylbutane on reaction with Br2 in the cold, darkness. 2.(2 points) Complete the following synthesis by filing in the missing...
Draw the major organic product from reaction of 1-butyne with 1 equiv Br2 Specify stereochemistry when it is relevant. In cases where there is more than one answer, just draw one. • Do not draw inorganic by-products. • If no reaction occurs, draw the organic starting material. OOO.
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