Question

You see below the frontier orbitals of an iron complex with C4v symmetry, described in a 4. recent article published by American Chemical Society's journal Inorganic Chemistry. You notice that three of the orbitals carry symmetry labels, while two do not. Assign the missing symmetry label or labels. (5 p) 2+ S 2 a1(d22) N- FeV (zr2p)q (dyex) b2(dxy) Fe (OX(N4py)12 Fe

Answer 1

The character table of Cau is born Cau E 24 G 200 20d Ali 1 1 1 1 A2 1 1 1 1 1 Bili - 1 1 B2 - 1 1 - E 12 0 -2 0. (Paz, 17) Here, dyz and dar are two degenerate orbitalie nt and ya akongas does not change independently. so duz = dyz must have belong to E g inaduceble, representation, ie foe, orbital it will be re a, (dz) - bi (chrony) at e (dyz, daz) 4 4 bz (day) +