8. The cesium iodide (CsI) molecule has an atomic separation of 0.127 nm. (a) Determine the energy of the second excited rotational state, with J 5 2. (b) Find the frequency of the photon absorbed in the J 5 1 to J 5 2 transition.
8. The cesium iodide (CsI) molecule has an atomic separation of 0.127 nm. (a) Determine the...
The equilibrium separation of H atoms in the H2 molecule is 0.074 nm. A) Calculate the energy of photons for the rotational transition ℓ=3 to ℓ=2. B) Calculate the wavelength of photons for the rotational transition ℓ=3 to ℓ=2.
In the line spectrum of hydrogen there is a ultraviolet line with wavelength 383.5 nm. The frequency of this line is ______ Hz. The energy is _____ J per photon, or ______ kJ/mol. This line corresponds to a transition from the excited state with n=9 to a lower state with n=2. The energy of the lower state is -5.45×10-19 J, so the energy of the excited state with n=9 must be ______ J.
6. Consider the bond vibration of a homo-atomic diatomic molecule. In the harmonic approximation the vibrational energy levels are given by, Where v = 0,1,..., and w = 6.1 x 1014 5-1. Let us assume this vibrational mode is IR active. A photon of energy E = hc/, is absorbed by the molecule and induces a fundamental vibrational transition. (a) What is the wavelength of the resulting IR absorption peak in nm? [6 marks] (b) Is it reasonable to assume...
1. A line in the spectrum of atomic mercury has a wavelength of 254 nm. When mercury emits a photon of light at this wavelength, the frequency of this light is 2. What is the energy of a photon of blue light that has a wavelength of 453 nm? 3. What is the wavelength of light that is emitted when an excited electron in the hydrogen atom falls from n=5 to n = 1? the wavelength of a 149-g baseball...
In scenario A, visible light has a wavelength of 700.6 nm. Determine its frequency, energy per photon, and color. frequency: s- 1 energy per photon: J The visible light in scenario A is In scenario B, visible light has a frequency of 5.657 x 10145-! Determine its wavelength, energy per photon, and color. wavelength: nm energy per photon: J The visible light in scenario B is In scenario C, visible light is yellow. Determine its wavelength, frequency, and energy per...
t kena lan LAST, FIRST, 6. Doubly ionized lithium, Lit2 which has 3 protons is in n 3 and excited state. All energies are in eV 2 state, the second (a) What is the energy value of the second excited state? (5 Pts) (b) It absorbed a photon making a transition from n = 3 to n = 5 state what is the wavelength of the photon absorbed? (5 Pts.) What are the possible final I values and the associated...
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At a given temperature the rotational states of molecules are distributed according to the Boltzmann distribution. Of the hydrogen molecules in the ground state estimate the ratio of the number in the ground rotational state to the number in the first excited rotational state at 300 K. Take the interatomic distance as 1.06 Å. Estimate the wavelength of radiation emitted from adjacent vibration energy levels of NO molecule. Assume the force constant...
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At a given temperature the rotational states of molecules are distributed according to the Boltzmann distribution. Of the hydrogen molecules in the ground state estimate the ratio of the number in the ground rotational state to the number in the first excited rotational state at 300 K. Take the interatomic distance as 1.06 Å. Estimate the wavelength of radiation emitted from adjacent vibration energy levels of NO molecule. Assume the force constant k-1,550 N m In...
8. (32 points) Scientists have studied excited electronic states of molecules by a variety of experimental techniques. The following data were obtained for an excited electronic state of Mgo. rotational constant, B = 0.5014 cm vibrational constant, .= 632.5 cm a) At what energy (in cm) and wavelength (in um, where 1 um = 10 m) will the J = 6 to J - 7 rotational transition occur for this electronic state of Mgo? b) What is the value for...
QUESTION 3: Atomic Structure 2 [25 total marks] (a) (1) What is the photoelectric effect? (2 marks) (ii) Find the frequency of incident photon on the surface of a metal if the threshold wavelength is 500 nm and the velocity of electron is 6 x 10 ms. (8 marks) (b) Considering the equation for the energy levels of a hydrogenic atom below, calculate the frequency of the transition between the ground and first excited electronic states of the hydrogen atom,...