6. Reaction Fill-ins. Predict the product(s) OR starting material of the following reactions. Put your answers...
Chem 202, Autumn 2019 Homework Packet 10 (Aldehydes and Ketones) 6. Reaction Fill-ins. Predict the product(s) OR starting material of the following reactions. Put your answers in the indicated boxes. NaOCI CH3COOH 1. NaBH4 2. H3O+ MgBr 2. Hz0+ H2Cr04 e. YYOH HyCros NaOCI OH CH3COOH 4 Page
7. Predict the product(s) OR starting material of the following reactions. Put your answers in the indicated boxes 1.NaBH4 ?? 2. H3O ?? HCrO ?? 2. H3O 1. NaBH 2. H3O 1. 2 LiAIH 2. H2O 1. excess CH3CH2MgBr 2. ???"
4. Reaction Fill-ins! Predict the product(s) OR starting material of the following reactions. Remember Hydride shifts are possible if when a more stable carbocation can exist (depending on reaction mechanism)! Put your answers in the indicated boxes. H2SO4 (cat.), H20 а. 1.4-product 1.2-product Br Br HBr b. Br Major product Minor produt Minor product HCI C. 1,2-product 1,4-product HI он MAJOR prod Minor prod. e. Draw the FULL electron-pushing mechanism for the reaction in part a above, INCLUDING ALL resonance...
4. Reaction Fill-ins! Prediet the product(s) OR starting material of the following reactions. Remember, Hydride shifts are possible ifwhen a more stable carbocation can exist (depending on reaction mechanism)! Put your answers in the indicated boxes H,SO, (cat), H,о а. 1,2-product 1,4-product Br Br HBr b. Br Minor produt Major product Minor product HCI C. 1,2-product 14-product HI Он MAJOR prod. Minor prod e. Draw the FULL electron-pushing mechanism for the reaction in part a above. INCLUDING ALL resonance contributors....
Chem 202, Fall 2019 Homework Packet 8 (Resonance and Aromaticity) 4. Reaction Fill-ins! Predict the product(s) OR starting material of the following reactions. Remember, Hydride shifts are possible if/when a more stable carbocation can exist (depending on reaction mechanism)! Put your answers in the indicated boxes H2SO4 (cat.), H20 а. 1,2-product 1,4-product Br HBr Br Minor produt Minor product Major product НC C. 1,2-product 1,4-product HI d. ОН MAJOR prod Minor prod e. Draw the FULL electron-pushing mechanism for the...
III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 H,Cro (excess) -CHO HO 17 1)0, (2 equiv.) 2) Mes (2 equiv.) 18 Ph Ph Ph Ph OH
2. Fill in the missing starting material(s), reagent, or major product(s) for the following reactions. ey NaBH4, H2O HO a. ? dy ? my HO HO
Fill in the missing starting material(s), reagent, or major product(s) for the following reactions. NaBH4, H2O HO ? by HO HO o
Draw the missing major organic product(s), starting material(s), or reagents for each of the following reactions (DO NOT WRITE +EN AS A PRODUCT (ie draw everything out!)! And remember stereo and regiochemistry.) Assume reagents are in excess unless otherwise indicated. **To make things simple, I indicated what is needed for each section! Please don't just put the answers, but explanations as well on why. Thanks! a) draw the starting material for this reaction. b) draw the product for this reaction....
Fill in the missing starting material(s), reagent, or major product(s) for the following reactions. NaOH a H J? ? heat (Show all major products) RCO3H ? (Show one major product)