Question

In the PE diagram, what is the RDS (rate determining step) for the forward reaction? Enter letters or numbers in the followin


5 с PE 6 2 В 1 A D Progress of Reaction amnte TI
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Answer #1

the above example step 3 i.e B → is the rate determining step because as  the rate is slow, so rate constant( k) value will be low

and according to Arrhenius theory if k is less high activation energy (Ea) is required

k= Ae-E/RT

where T is temperature at which the reaction is occurring

R = universal gas constant

A =pre exponential factor

as seen in the PE from going B to C huge activation energy is required which means more energy has to be supplied to push the reaction in the forward reaction so it is the rate determining step

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