Element of unsaturation or Index of Hydrogen deficiency or double bond equivalence: = [2( number of carbon atoms) -( number of monovalent atoms ) + ( number of trivalent atoms) +2] /2
a) = (2*3 -3 +3 +2)/2 = 4
This molecule can have four double bond or two triple bond or mixture of double / triple bond / ring.
b) = (2*5 -5 -3+2) /2 = 2
This can have two double bonds or 1 triple bond or 1 double bond + 1 ring
Given the following molecular formulas calculate the elements of unsaturation for each compound. (4 points) C3H3N3...
2. For each of the following molecular formulas, determine the number of elements of unsaturation, and draw three examples. 8pt a) C&H CINO b) CHIO
SHORT ANSWER AND DISCUSSION. 4. Calculate the degrees of unsaturation for each of the following molecular formulas and draw a structure is consistent. Show your work! [8 points] CHgCl2 CH, NO 5. In class, we discussed the following reactions and how they differ in their regioselectivity. Provide the product for each reaction and discuss why the regiosclectivity is observed in each case. Draw diagrams to explain your answer. [8 points). 1) BH3. THE 2) H2O2, OH H2O H2SO4
Given the molecular formula calculate the degree of unsaturation for the following compound C8H9NO3. And what are three possible structures consistent with the degree of unsaturation for the compound?
Given the molecular formula, calculate the degree of unsaturation for the following compound. Suggest at least three possible structures consistent with the degree of unsaturation for each compound. (Special case: A nitro grou, -NO_2, has one degree of unsaturation. This information doesnt matter when you are calculating the degree of unsaturation, but it might matter when you start drawing structures.) C_3H_14O_2 C_2H_30 O C_5H_10 O C_4H_9NO_3 C_4H_4O_2 C_2H_10 Cl_2
2. Calculate the degree of unsaturation in each of the following molecular formulas: a. C2oHs7Br d. C12H1oN20 e. C1oH NO2
QUESTION 3 Calculate the degree of unsaturation for the following molecular formulas CioH16
Calculate the units of unsaturation present in compounds with the following molecular formulas. Draw a structure consistent with the molecular formula and your calculated units of unsaturation. a) C6H10O b) C7H11N0 c) C2H2BrN d) C10H7CIO
Give 3 possible molecular formulas for a compound with a molecular ion peak of 148 and calculate the degrees of unsaturation for each compound. Please show work
Calculate the degree of unsaturation in the following
formulas, and draw five possible structures for each:
3. Calculate the degree of unsaturation in the following formulas, and draw live poss unsaturation in the following formulas, and draw five possible structures for each: 1) Cg Ha No 2) C&H CINO
Compound A has the molecular formula C10H14.
a) Calculate the unsaturation number or IHD.
b) Provide the molecular ion observed in the mass spectrum,
including its units.
c) Propose a structure based on the carbon-13 NMR spectrum
given.
CH3 CH Compound A CDCl3 160 140 120100 80 60 40 20 0
CH3 CH Compound A CDCl3 160 140 120100 80 60 40 20 0