a) Singlet will appear
Explanation: There are no coupling partners for the protons of methyl group (3H).
b) Doublet will appear
Explanation: The 6 protons of two methyl groups couple with 19F, multiplicity of the signal = 2nI + 1 = 2*1*1/2 + 1 = 2 (doublet)
c) Doublet will appear
Explanation: The 6 protons of two methyl groups couple with 77Se, multiplicity of the signal = 2nI + 1 = 2*1*1/2 + 1 = 2 (doublet)
d) Triplet of doublet will appear
Explanation: The 3 protons of methyl group first couple with 19F, multiplicity of the signal = 2nI + 1 = 2*2*1/2 + 1 = 3 (triplet), followed by coupling with 31P, multiplicity of the signal = 2nI + 1 = 2*1*1/2 + 1 = 2 (doublet). Hence, each line of the triplet will further split into doublet, i.e. triplet of doublet.
e) A triplet and a quartet (two different signals) will appear.
Explanation: triplet appears for the protons of 2 methyl groups (6H), quartet appears for the protons of two methylene groups (4H).
Relevant i = 12 nuclei and relative natural abundances are as follows (assume all other nuclei...
number 2 Relevant i = 12 nuclei and relative natural abundances are as follows (assume all other nuclei are spin inactive): 19F (1 = /2, 100%) TH (1 = 12, 100%) 295i (1 = 42, 4.7%) 31P (1 = /2, 100%) 77 Se (1 = 12, 7.6%) Also, assume 1 > 2/> 34, there is no resolvable 4 coupling, and there is no observable coupling to 13C nuclei. 1. Using stick diagrams, sketch the TH NMR spectra for the following...
sketch and explanation please Relevant i = 12 nuclei and relative natural abundances are as follows (assume all other nuclei are spin inactive): 1H (I = 2, 100%) 29Si (1 = 42, 4.7%) 19F (I = 2, 100%) 31P (1 = /2, 100%) 77Se (1 = %, 7.6%) Also, assume 1 > 2/> 34, there is no resolvable 4 coupling, and there is no observable coupling to 13C nuclei. Using stick diagrams, sketch the TH NMR spectra for the following...
number 2 sketch please Relevant i = 12 nuclei and relative natural abundances are as follows (assume all other nuclei are spin inactive): 19F (1 = /2, 100%) TH (1 = 12, 100%) 295i (1 = 42, 4.7%) 31P (1 = /2, 100%) 77 Se (1 = 12, 7.6%) Also, assume 1 > 2/> 34, there is no resolvable 4 coupling, and there is no observable coupling to 13C nuclei. 1. Using stick diagrams, sketch the TH NMR spectra for...
number 2 sktech and explanation please Relevant i = 12 nuclei and relative natural abundances are as follows (assume all other nuclei are spin inactive): 19F (1 = /2, 100%) TH (1 = 12, 100%) 295i (1 = 42, 4.7%) 31P (1 = /2, 100%) 77 Se (1 = 12, 7.6%) Also, assume 1 > 2/> 34, there is no resolvable 4 coupling, and there is no observable coupling to 13C nuclei. 1. Using stick diagrams, sketch the TH NMR...
Relevant I 2 nuclei and relative natural abundances are as follows (assu me all other nuclei are spin inactive): H(I 100%) 19F (I, 100%) 77Se (I2, 7.6%) 29Si (I 4.7%) 31P (I 2, 100%) Also, assume 'J 2J> 3J, there is no resolvable 4J coupling, and there is no observable coupling to 13C nuclei. Using stick diagrams, sketch the 'H NMR spectra for the following compounds. Assume structures are rigid in solution (give all isomers). Include all relative peak intensities...
Name: 2.2 Hydrogen The relative isotopic abundance for hydrogen 2H: 1H is about 0.00016: 1, and therefore hydrogen isotopic substitutions are unlikely to play a major role in any observed (M+1) peak. The isotope 2H is called "heavy hydrogen or deuterium, and is given the symbol D. We can often provide support for mechanisms by incorporating isotopes such as 13C or D into compounds using isotopically labelled reagents. Mass spectrometry is a useful tool for analyzing such isotopic incorporation by...