Question
What is the final product for the following reactions?
What is the final product for the following reactions? (S pts) 2. 1DBr, FeBr 2) H2SO4 HNO 3) H,SO, (fuming) 1)H,SO, HNO 2) HS
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Answer #1

in below reaction first step is bromination occur para to tert-butyl group

the second step is nitration occurs ortho tert-butyl group

the third step is sulfonation occurs ortho to tert-butyl group and meta to nitro group

FeBr3 ON HNO H2SO4 Br Br Br H2SO4 НO S NO2 Br

in below reaction first step is nitration occur para to tert-butyl group

second step is sulfonation occurs ortho to tert-butyl group and meta to nitro group

third step is bromination occurs ortho to tert-butyl group and meta to nitro group

SO3H H2SO4 H2SO4 HNO NO2 NO2 FeBr3 Br. HOOS NO2

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