1. For each of the following reactions, provide the structure of the major organic product(s). Show...
Draw the structure(s) of the major organic product(s) of each of the following reactions. Be sure to indicate stereochemistry when it is relevant. CH3CH2 H CH2CH3 (15) 5 CH2CH3 CHE CM H3PO4 H C H CH₂ CH3 (E1) CH3 CH₃ CH2 Pou-Y CH3CH2, H HOBCH2CH3 Na+OCH2CH3 CH₃ nov (12) x CH3 (15) d. en Ha CH OCH₂ CH₂ - 4 CH CH₃ -9 CH₂ CH2
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. C(CH3)3 NASH Br (S)-2-bromononane - acetonitrile KOH CH,OH NaCN HE Br Acetonitrile C2H5 H, Br NaOH Acetone excess HBr ROOR HC1 + Br Na o DMSO
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. H2, Pd/C Cla, hv A) Br CH2OH B) C) CH2CH2CH2OH H2SO4 NaBH4 SOCI2 D) H CH3CH2OH TEA OTS CH3 SNa E) DMSO OH PCC...
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. КОН (alc) Br b) KOtBu HOtBu Br THE H2SO4 OTS КОН (ale) CH,CH Show Specific Stereochemistry CH(CH3)2 HCI H- CH CH_CH KOH (ale) Show Specific Stereochemistry NaOCH HOCH KO:Bu HOBu
Complete the following reactions by drawing the structure of the
major organic product.
( CH3 mCPBA CH₂O₂ show dash-wedge CH3 (1) LiAlH draw a chair conformation (2) H30+ NaB (CN) Hz H LII2 C5H1N CH2OH solvent
use the above guidelines to predict the major organic product of
the following reactions.
JPB 2020 8.18 Points -Exception-substitution can occur with weak bases (CN, N3, SH, SR) -Exception-3° alkyl halides undergo substitution (solvolysis) with alcohols. 3. Use the above guidelines to predict the major organic product of the following reactions. (5) CIK* -OC(CH3)3 CH3 C. CH3CH2-C-CH3 + CH,OH — Br + CH20- CH2OH n o -Br + NACN + NaCN - DMSO DMSO
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. excess HBr ROOR HC1 + Na o BⓇOS DMSO
3. Shown below are a series of reactions. Predict the major product for each of them. Remember, you will need to first decide whether the reaction occurs by an SN2, SN1, E2, or E1 before you can determine what the product will be. Label each as SN2, SN1, E2, or E1. Hint: First decide whether S2/E2 or S1/E1 is favored, and then decide whether the reaction pathway goes by a substitution or elimination reaction. SN2 / SN1 E2/E1 Na DMSO,rt...
1. For the following reactions, show the major organic product(s) in the box provideed. Make sure to show appropriate stereochemistry wherever necessary. Underneath the box, mention the mechanism (SN1, El, S2, or E2) that leads to the major products and also show the arrow pushing mechanism. Understand that the compound listed below the arrow is solvent. (a) Br O Na DMSO Mechanism: (b) NaOH Н-о Mechanism: Organic Chemistry C341 (e) CHCH Oн 4 Mechanism: (d) NaOMe E1OH Mechanism: (e) BeOK...
• Please provide the major organic product(s) of the reaction as described. Account for all stereochemistry requirements for reaction and products. You need not include byproducts such as salts for this assignment, but you should be aware of their presence. "No reaction" is NOT a possibility on this assignment. Starting Material Conditions Major Product(s) ОН PB13 Et20 NaCN OMs DMF Br NaNH2 DMSO, 20'C 8 hr