9). The structure at the right is found to have [a]p = +24.3º. A) (3 pts)...
9). The structure at the right is found to have a lo = +2439 A) (3 pts) Draw the structure of the stereoisomer that might have a los 24.3° B) (3 pts) Draw the structure of the stereoisomer that has no optical rotation C) (4 pts) A graduate student tries to synthesize the structure and finds his product has no optical rotation. Provide two possible explanations for that outcome.
9. (3 pts each) If a name is given, draw the structure, clearly showing all substituents and their locations. If a structure is given, provide a name. a. 7-bromobicyclo[3.2.1 Joctane
2. Provide the missing products/reagents for the following reactions (2 pts each, 12 pts) 3. Protecting groups are important in Organic synthesis. We have seen 3 different protecting groups so far. Pick one and show how it is added, how it is removed, and what unwanted reactivity of the starting functional group it avoids. 4 pts) It is actually possible to oxidize ketones to esters using a reaction we have not talked about the Baeyer Villager reaction - which uses...
5) (8 pts) Arrange the following compounds from most acidic through neutral to most basic. Briefly explain your reasoning. 7) (15 pts) a) Write out the 3-step arrow pushing mechanism showing how 1-pentene is hydrated to make 2-pentanol. b) Draw the other 2 alkenes (don't forgel cis/trans isomers!) that could also be hydrated to make 2-pentanol. Briefly explain why 1-pentene is the best choice. II, II,O a) heat Acidic Neutral Basic 6) (18 pts) Consider the Fischer projections of the...
5. D-sorbital is found in 'sugar-free' chewing gum. It is formed by reducing D-glucose with NaBH Draw the structure of D-sorbital. s. (4 pts) Classify the following amino acid as polar, non- polar, acidic, or basic: 6 (4 pts) The amino acid threonine (thr) has two chiral carbons. Draw a Fischer projection of the 2S,3S configuration of threonine. キ 7.(11 pts) Draw the tripeptide lys-asp-ser at physiological pH 8. (8 pts) The pK, values for aspartic acid are 2.10, 9.82...
(3 pts) In a college student poll, it is of interest to estimate the proportion p of students in favor of changing from a quarter-system to a semester-system. How many students should be polled so that we can estimate population proportion to within 0.09 using a 99% confidence interval? A small study has been done, that found a sample proportion of 0.35
Suppose you have the following value function: u(z) 2 r for gains and v(z) 3r fr losses. You have aeowment of 4 apples and 3 bananas, draw your indifference curve given the value function Problem2 1) Suppse Dr Wu has four siblings. You know the oldest and the youngest of Dr Wu's siblings are men. What is the relevant outcome space now? (Order matters!) 2) Please answer true or false for the following questions and provide explanations . You are...
Suppose you have the following value function: u(z) 2 r for gains and v(z) 3r fr losses. You have aeowment of 4 apples and 3 bananas, draw your indifference curve given the value function Problem2 1) Suppse Dr Wu has four siblings. You know the oldest and the youngest of Dr Wu's siblings are men. What is the relevant outcome space now? (Order matters!) 2) Please answer true or false for the following questions and provide explanations . You are...
Pleqsw help with this question
3. (a) Consider the bond-line (dash/wedge) structure shown below. Using the Newman projection templates provided to the right of this bond-line structure, draw the overall lowest energy (most stable) and overall highest energy (least stable) conformation possible in Newman projection form sighting down the C C, bond indicated. Provide a one sentence explanation to justify for the overall most stable conformation. (Ipts each correct Newman, 2pts for valid explanation) sight down Cy-- - bond .23...
can someone answer 14-17
Genome structure (4) 14. (4 pts) Humans have about 20,000 protein genes encoded in a genome of about 3 billion bp. Rice has about 37,000 protein genes in 300 million bp. How might you explain this difference in gene density? Nuclear organization (14) 15. (6 pts) Describe the structure of a nucleosome. 16. (4 pts) How does chromatin structure affect gene expression? 17. (4 pts) Give two examples of specific chemical modifications which control chromatin structure.