Question

Part A Which of the following pairs of coordination compounds or complex ions are examples of ionization isomers? [Fe(NH3)2(H20)4]Cl2 and [Fe(NH3)4(H20)2Cl2 [Cu(CO)gBr]CI and [Cu(CO), CIJBr [MnCl3Br]2- and [MnCIBr312- [Fe(NH3)2(H20)4]C12 and [Fe(NH3)2(H20)4]Br2 [Fe(CO)NO12+ and [Fe(CO) ONO]2+ Submit Previous Answers Request Answer

Answer 1

Isomers must be have same molecular formula.

mea PARTA Ionisation Isomerism » This type of Isomerism occurs when the counter ion in a Coordination compound is itself a potential digand. (Same molecular formula with different counter) ion ) oll [fe crim2420),] U s [fe CriMady (H2O),] ₂ I no lonization I usomer's (pe l nm),(40.3*4246 [Le cam3,670x7"? +24° Cor [au (co), Brja --> [Cco, Bo]* +007 [cu (co), ca] B [colo),u]* Bro Isomery 01 [Mnuz by]2 - No Jonization Isomers - [Mn 4 Bos] 2 011 [Fe (mm), liko), Juz —> [ (), (422)]*+2007 No [Fe (143) (420,]Boy - [Fe (N43),420),742 + 280 Jusomer Answer Belanse of different molecular formula oll [Fellos (felco), No2]*(re (Co), ono]2+ No counter clon Isomerism so no Ionization

PART A Answey - linkage Isomers - When any complex have Ambidentate ligannel shows linkage usomerismi (due to different donar site in both Form] [eko) moz]*2 s [Fe (CO), oro]*2 donar site donar . sité Nitrogen . oxygen same structural isomerism as in which molecular formula with different structures eig. o link ange isomerism 0 Ionization : 1 ④ Hydrate lo ① ligand ... on o coordination s', Answey - linkage isomers