Question

Which of the wavelengths listed below is absorbed most by the crystals in potassium hexacyanoferrate(III): K3Fe(CN)6...

Which of the wavelengths listed below is absorbed most by the crystals in potassium hexacyanoferrate(III): K3Fe(CN)6

a) 410 nm

b) 480 nm

c) 560 nm

d) 610 nm

e) 720 nm

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Answer #1

Crystals in potassium hexacynoferrate(lll) : K3Fe(CN)6

absorbed the wavelength is 410nm.

In general low spin complex absorb lower wavelength due to strong field ligands which split the d-orbital to greater extent.so the transition required higher energy.

Thus option (a) is correct.

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