Question

. 2Y2 V 2Hy lag) t 2u- lag

Electrochemistry Comparison reference electrodes Calomel Silver/silver chloride SHE 1 기체 1기압 SnKC Gaden KC Cr Pet IM KCL3.Sl


To draw the cell diagram of SHE and Calomel el, possibly a structure of the procedure occurring.
The only information I have of this problem is shown in the pictures.

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Answer #1

1. The half cell reaction for standard hydrogen electrode is given by, 2H+ (aq) + 2e- = H2 (g)

The SHE is constructed by immersing a platinum electrode in a 1 M solution of H+ and hydrogen gas is blown into the solution at 1 atm. pressure.

The cell representation is as follows:

Pt(s)| H2 (g. 1 atm) H+ (aq. 1 M)||

1. The half cell reaction for calomel electrode is given by, Hg2Cl2 (s) + 2e- = 2Hg (l) + 2Cl- (aq)

The calomel electrode is constructed by a pool of mercury covered with a paste of calomel (mercurus chloride) and a solution of KCl.

The cell representation is as follows:

cr (aq, C1) HgCl2 (5) Hg | Pt

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