Question

Solve for the pH of a 1.00L solution that is 0.25 M HC3H502 and 0.45 M KC3H502 when 0.100 moles of NaOH are added. [base] pH

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Answer #1

after 0.100 moles NaOH added following reaction takes place.

[HC3H5O2] = 0.25 - 0.100 = 0.15 M

[C3H5O2] = 0.45 + 0.100 = 0.55 M

pH = pKa + log [C3H5O2] / [HC3H5O2]

pKa = - log Ka = - log 1.3 x 10-5

pH 4.89

pH = 4.89 + log [0.55] / [0.15]

pH = 5.45

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