Homework Answers
a) An ether solvent is generally diethyl ether which is almost a nonpolar organic solvent. It favour the formation of a free radical more than formation of ions.
b) The general formula of peroxide is R2O2 where R may a hydrogen or alkyl group or alkanoyl group like C6H5CO.
C) It is the chemistry of regioselective reaction. A reaction in which formation of one structural isomer is favored over all other products is known as regioselective reaction. For example propene upon reaction with HBr in absence of a peroxide gives 2-bromo propene as the major product and 1-bromopropene as minor product.
d) Polarity refers to separation of two opposite charges by a certain distance. A molecule is said to be polar if it has opposite charge poles. A polar solvent contain polar molecule. Polarity in a molecule develops due to difference in electronegativity between atoms in a molecule provided molecule is not symmetrical. Water is classical example of polar solvent.
e) Stability of simple alkene is decided by hyperconjugation. Greater is number of hyperconjugation interactions, Greater is stability.
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13. When HBr is added to a simple alkene containing peroxides, the regiochemistry obtained is in...
f. From your knowledge of the radical addition mechanism, what product would you expect from the...
f. From your knowledge of the radical addition mechanism, what product would you expect from the treatment of 1,3-butadiene with HBr in peroxide containing ether. Support your answer by showing the mechanism for the reaction and the role played by the peroxide. (6 pts)
1.1What is the major product formed upon radical bromination of (S)-3-methylhexane? Select the best response. Draw...
1.1What is the major product formed upon radical bromination of (S)-3-methylhexane? Select the best response. Draw the full mechanism. A. (S)-3-bromo-3-methylhexane B. (R)-3-bromo-3-methylhexane C. A mixture of (R) and (S) 3-Bromo-3-methylhexane D. (3R)-1-bromo-3-methylhexane 1.2 What is the major product obtained from the reaction of 2-methyl-2-butene with hydrogen bromide in the presence of peroxides?Select the best response. Draw the mechanism. A. 2,3-dibromo-2-methylbutane B. 2-bromo-3-methylbutane C. 2-bromo-2-methylbutane D. (E)-1-bromo-2-methyl-2-butene 1.3 There are 4 major products formed upon treatment of (E)-3-methyl-2-hexene with HBr...
Alkene reaction and mechanisms practice exercise 1) O₃ 2) (CH3)2S 25) Treatment of cyclopentene with peroxybenzoic...
Alkene reaction and mechanisms practice exercise
1) O₃ 2) (CH3)2S 25) Treatment of cyclopentene with peroxybenzoic acid A) results in oxidative cleavage of the ring to produce an acyclic compound B) yields a meso epoxide C) yields an equimolar mixture of enantiomeric epoxides D) gives the same product as treatment of cyclopentene with Os04 E) none of the above 26) Provide a detailed, step-by-step mechanism for the reaction shown below. но Br2 na + HBT Br 27) Provide a detailed,...
How to solve alkene and alkyne reactions - Merdanym i Act antalyzod Hrdian ca Come Lazarmistry...
How to solve alkene and alkyne reactions
- Merdanym i Act antalyzod Hrdian ca Come Lazarmistry I V WORKSHOP #9 Alkenes, Alkynes, Reactions 1. Give a reasonable mechanism for the following reaction. Clearly show intermediates and show the movement of electron pairs with curved arrows. all сна H20. (H2SO4) H₃C CH₂ нас он H3CX сна 2. The addition of HBr to 2-methylpropene can, in principle, give either 1-bromo-2- methylpropane or 2-bromo-2-methylpropane. In reality, only the latter is formed. Show mechanisms...
Only need help with 5,6,7 and mechanism FTIR and NMR Spectra After completing a reaction and...
Only need help with 5,6,7
and mechanism
FTIR and NMR Spectra After completing a reaction and working up the products, it is still necessary to confirm that the correct product was formed. The most common tools used for this analysis are Fourier Transform Infrared (FTIR) and Nuclear Magnetic Resonance (NMR) spectroscopy. In the virtual laboratory, 'H and C NMR spectra are available. Details on interpreting FTIR and NMR spectra are found in your textbook. Your instructor may or may not...
f. From your knowledge of the radical addition mechanism, what product would you expect from the treatment of 1,3-butadiene with HBr in peroxide containing ether. Support your answer by showing the mechanism for the reaction and the role played by the peroxide. (6 pts)
Alkene reaction and mechanisms practice exercise
1) O₃ 2) (CH3)2S 25) Treatment of cyclopentene with peroxybenzoic acid A) results in oxidative cleavage of the ring to produce an acyclic compound B) yields a meso epoxide C) yields an equimolar mixture of enantiomeric epoxides D) gives the same product as treatment of cyclopentene with Os04 E) none of the above 26) Provide a detailed, step-by-step mechanism for the reaction shown below. но Br2 na + HBT Br 27) Provide a detailed,...
How to solve alkene and alkyne reactions
- Merdanym i Act antalyzod Hrdian ca Come Lazarmistry I V WORKSHOP #9 Alkenes, Alkynes, Reactions 1. Give a reasonable mechanism for the following reaction. Clearly show intermediates and show the movement of electron pairs with curved arrows. all сна H20. (H2SO4) H₃C CH₂ нас он H3CX сна 2. The addition of HBr to 2-methylpropene can, in principle, give either 1-bromo-2- methylpropane or 2-bromo-2-methylpropane. In reality, only the latter is formed. Show mechanisms...
Only need help with 5,6,7
and mechanism
FTIR and NMR Spectra After completing a reaction and working up the products, it is still necessary to confirm that the correct product was formed. The most common tools used for this analysis are Fourier Transform Infrared (FTIR) and Nuclear Magnetic Resonance (NMR) spectroscopy. In the virtual laboratory, 'H and C NMR spectra are available. Details on interpreting FTIR and NMR spectra are found in your textbook. Your instructor may or may not...
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