Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4...
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i) Pd/C OsO4 NaHSO3, H20 н СHC1, КОН (iv) i) ВН, THF CECH in) H,О, NaOH Li, NH3 (liquid) (vi) XX H/H20 (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. он BH3, THF i)H202 NaOH он )Hg(OAc)2 H20 i)NaBH (iii CH O i) Zn/H +
3. Predict the majoe product(s) for the following reactions. Show the stereochemistry of the product(s) when applicable. HCI (1) Hg(OAc)2 (2) NaBH4 (1) BH3 THF (2) H202. OH Br, Br2. H20 Pt (I) CH3CO3H (2) H,O+ (2) DMS HBr ROOR
I need help with detailed steps of the reactions , thank you ! 3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). 05-0 YBY TH Brz in H2O 1.0 2. Mes CHO H/Pd 1. Hg(OAc), in THF/water 2. NaBH, NaOH 1. BH -THE 2. H2O2, NaOH peroxyacid HBO HBr/peroxide 1. OsO4 2. NaHSO3
22. Predict the major product for the following reactions. OsO4 CH3 CH3COOH н* / H50 H2O2 HBr / peroxide 1. Hg(OAc)2, THF, CH3OH 2. NaBH4, HO 1. Which of the following has 2 elements of unsaturation? CH3-CH2-CECH N I all of these (A) (D) (E) Which of the following best describes the geometry about the carbon-carbon double bond in the alkene below? CHO (A) E (B) Z (C) neither Enor Z 3. Which of the following alkenes violates Bredt's rule?...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Draw the major organic product for each of the following reactions. The first and third product are correct, but the second one is not. I am getting a hint for the second one that: "a rearrangement will occur before water additions." Thanks. Draw the major organic product for each of the following reactions. 1. BH3, THF 1. Hg (OAC)2, H20 2. NaOH, H20, H202 H2SO4 2. NaBH4 H20
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following reactions. Indicate stereochemistry and regiochemistry when appropriate. Indicate reactions that are expected to result in a racemic mixture of products DBr 1. Н.О, CHCI он HSO, heat кон 1) вн, THF 3. 2) H202. HO 1) Hg(OAc)2, CH,OH 2) NaBH, OH 5. Br2 SH 6. HIO4 OH THF, H2O "он III. Synthesis: Starting from the alkenyl bromide below, devise a synthesis that produces the...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
Provide the major organic product (including stereochemistry if appropriate) for each of the following reactions: 3. 1) NaH а) (CH)-СHCH,ОН 2) (CH),СНОСH-CH,Br b) excess HI 1) Hg(OAc),/H,O 2) NaBHĄ/HO¯ 1) NaOH 2) PҺOH d) CH,CH,Br 1) BH3/THF 2) H-0,/Но" НCIZnClz он g) MCPBA h) 1) mCPBA 2) CH3O¯ 1) mCPBA 2) CH,ОН/Н"
1. [6 points] Predict the major product/s of the following reactions. Indicate stereochemistry using dashed and wedged bonds where appropriate 1. BH2 and THF 2. NaOH and H202 H30 H20 CI H20