Addition Reactions:
Reaction 4, Reaction 5, and Reaction 7 are examples of addition reactions.
Explanation: In these reactions, unsaturated compounds converted into saturated compounds by the addition of the added reagent.
Elimination Reactions:
Reaction 1 is the elimination reaction.
Explanation: In this reaction, the saturated compound is converted into the unsaturated compound by the elimination of a small molecule (HCl).
Substitution Reactions:
Reaction 2, Reaction 3, and Reaction 6 are examples of substitution reactions.
Explanation: In these reactions, one of the atom/group on the specific carbon atom is substituted by another atom/group.
Classify each of the following organic reactions. Addition CH3-CH2-CH-CH3 – CH3-CH2-CH=CH2 + HCI CH3-C-O-CH3 + CH3-NH-CH3-C-NH-CH3...
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH + HCN– CH3-CH-CN CH3-CH2-CH2-OH + HBr – CH3-CH2-CH2-Br + H2O CH3-CH=CH-CH3 + HBr – CH3-CH-CH2-CHz Br
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction CH3-CH2-CH2-CH3 + Cl2 → CH2-CH2-CH2-CH3 + HCI CI CH3-CH=CH-CH3 + Cl2 → CH3-CH-CH-CH3 CICI CH3-CH2-CH-CH3 - CH3-CH2-CH=CH2 + HCI
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
4. Classify each of the following reactions as: Acid/ Base, Addition, Elimination, Reduction, Oxidation, Condensation, or Hydrolysis. (7 points each) a. CH3CH2OH [O] + CH3-CH (H2) [O] P → CH-E-OH (+0) (conc. Acid and heat) b. CH3-CH2-CH2-OH CH3-CH=CH2 + H2O (Pt cat) c. CH3-CH=CH2 + H2 → CH3CH2CH3
A.
Classify organic reaction below as either addition, elimination,
rearrangement or substitution. For each reaction predict whether
deltaS>0, deltaS<0, delta S~0
B. For reaction iv the equilibrium constant has been measured
as K=195. Calculate deltaG for this reaction at 25deg C giving
answer in KJ/mil. ( the most convenient form of R for this
calculation is R=8.314J/mol/K.
C. Using answer to (b) and (c) predict the sign of deltaH for
reaction (iv)
Cl OH +C Br + 2 HBr Br...
name the following organic compounds
Name the following organic compounds: CH CH, --CH2-C-CH CH CH3-CH2-C1 CH3-CH, Br CH3-CH2-CH-CH2-CH-CH3 Br CI-CH2-CH-CH2-Br Сн, CH-CH-CH-CH: CH3 CH, ---CH2-C-CH2-CH;
1. Classify each of the following reactions as either an addition, elimination, substitution, or rearrangement ОН SOCI, Br Br2 1 equiv. Br ОН Он H,SO, + H20 heat ОН CH* 1. OsO4, 2. Н,О, "ОН molten KOH 200°C Br Br
Name the following organic compounds. Please explain.
ÇHz—CH CH3-CH-CH2 - CH2 - CH2-OH H3C- N- CH3 CH3 17. CH2-CH-CH2-CH2-O-CHZ CH2-O-CH3 CH3 18. 19. CH3 CH3 CH2 - CH-CH-C- CH2 CH2 - CH - CH2 - CH2-C-H CH CH3 Pongracando con 20. CH3 -CH-CH2-CH-C-OH 21. CH, -CH-C-CH=CH2 CHZ CHE 22. CH3-CH - CH2 - CH2 - C -0 - CH3 23. CH3-CH2—6- NH-CH3 CH CH CI CH2 - CH2 25. CH2 - CH3 CH2 - CH3 HO 27. ÇH2CH-CH2 ӧн Онон
1.(2 pts) Classify the following ADDITION reactions as oxidation, reduction, or neither. Reaction Type CH,CH-CH=CH2 → CH3CH2CHCH2OH Cl Cl 2.(2 pts) Which energy diagram shown below BEST represents an E1 reaction? Rnx Rnx 3.(4 pts) Complete the following reactions as given. CH CH3 CHj 4.(2 pts) Underneath each compound write YES if it could be obtained from the reaction substrate A with NBS and NO if it could not. Br
Pre-Lab Study Questions 1. Give the IUPAC name for each of the following: 1. CH-CH2-CH2-C-OH DUHOInoic acid b. CH3 -CH2-C-0-CH-CH, einyl propionic acid C. CH-CH:CH-ch-c-o pentanoic acid 2. Write the condensed structural formula of the organic product for propanoic acid reacting with each of the following: a. NaOH b. CH, --OH c. HO 3. Write the condensed structural formula of the organic products for ethyl ethanoate when it reacts with each of the following: a. NaOH b. H20 and HCI