Question 1 1. Using an equation like equation 3, derive the expression for k given in...
using an equation like eq 3, derive the expression for k given
in eq 4
Equation 3 Co2 2.303 log [R-CIDO [R-Cl]o - 0.5[R-CN) kt1/2 = 2.303 log 2 = k = 0.693 / 112 Similarly, we can also solve fork in terms of t1/10, the time required for one-tenth of the starting material to react. Equation 4 k = 0.1054 /t 1/10
in
the solvolysis of 2-chloro-2-methylpropane, some di-t-butyo ether
is formed. Explain rhis phenomenon in your own words and show the
reaction sequence that represents this, starting with your starting
materials.
Complete and turn in the problems below. 1. Using an equation like equation 3, derive the expression for k given in equation 4. 2. What solvent mixture are you using in parts A-C? In part D? What effect will the different solvent system used in part D have on the...
ln(k) = -E_a/R 1/T + ln(A) A plot of ln (k)versus 1/T result in a straight line with a slope = -E_a/R. The value of E_a can then be calculated using the value of R and to the slope of the line. This experiment uses the Arrhenius equation, which relates the temperature and specific reaction rate constant to determine the activation energy for the crystal violet reaction. The reaction will be performed at different temperatures. Once the order of reaction...
pt took 3 minutes. Question 1 0/1 pts According the the Arrhenius equation, how you can increase the reaction rate? In other words, how can you make k (the rate constant) larger, which leads to a faster reaction? increase the temperature increase the fraction of collisions that result in a successful reaction (the frequency actor
2) Rank the nucleophiles given below based on high, mediocre,
and low nucleophilicity and reason why based on their structures.
HO-CH3, H2N-CH3, KO-CH3, KO-C(CH3)3
Introduction Alkyl halides can be prepared from alcohols by reactions with hydrogen halides (HCI, HBr, or HI) via nucleophilic substitution. In this type of reaction, the nucleophile displaces a leaving group from a carbon atom of an organic substrate (here the alcohol once protonated). Both electrons of the new bond to the carbon are provided by...
1) State which of the electrophiles given below will react
preferentially by i) SN1, ii) by SN2, or iii) capable of reacting
by either of the two mechanisms depending on the given conditions.
How can you affect those conditions to favour SN1 or SN2? Reason
your predictions based on the structures of the compounds. Br-CH3,
Br-CH2CH3, Br-CH(CH3)2, Br-C(CH3)3, Br-CH2-C5H6; C5H6 = phenyl
Introduction Alkyl halides can be prepared from alcohols by reactions with hydrogen halides (HCI, HBr, or HI) via...
3) Name two solvents that are commonly used for SN2 reactions.
because they considerably slow down SN1 reactions.
Introduction Alkyl halides can be prepared from alcohols by reactions with hydrogen halides (HCI, HBr, or HI) via nucleophilic substitution. In this type of reaction, the nucleophile displaces a leaving group from a carbon atom of an organic substrate (here the alcohol once protonated). Both electrons of the new bond to the carbon are provided by the nucleophile while the leaving group...
2. Using the decay chain for 238U, calculate the amount of time it takes 5.0 kg of 238U to decay to 2.5 kg. What mass of 206Pb is produced? (5 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ ΔGIRT Ke=e AGⓇ = -nF8° Units/Constants: Volt: 1 V=1/C Faraday: 1 F -96,485 C/mol e Arrhenius Equation: k = Ae Ea/RT R= 8.314 J/mol K Integrated Rate...
hi
can You please solve [t-BuCl] remaining for my table
the concentration of it remaining
I only used time trial attempt 1
heres my data with the table thats not filled in on the
picture:
for % t-BuCl remaining for trials 2-4:
I got 85 % trial 2, 90 % trial 3, and 95% trial 4
for trials 1-4 for time 1st attempt I got
87 seconds trial 1
72 seconds trial 2
35 seconds trial 3
7 seconds trial...
Ch 15 Extra credit opportunity. 10 pts max. Due By Exam 2 (11/14). 1)If you are enrolled in or have previously taken calculus, derive the integrated rate equations for oth, 1st and 2nd order reactions. (2 pt ea, 6 pts) Hint, start with the instantaneous rate law, expressed as differential rates, Such as d[A]/dt = k. Separate your variables, d[A] to one side, dt to the other. Integrate from time 0 to time t and simplify. Show every step. 2)...