#1. Mole concept ;
1 mole of every substance in UNIVERSE = molar mass of that substance = 6.022×10^23 atoms/ions/molecules (Avogadro's no.)
So now as , 1 mole of carbon dioxide (CO2) = 44g/mol (molar mass)
So , 44g CO2 have molecules = 6.022×10^23 molecules
Then 154g CO2 will have molecules = (6.022×10^23molecules/44g CO2) × 154g CO2 = 2.11×10^24 molecules of CO2
Option D is correct .