80. Design a multi-step synthesis using only the reagents provided in the box. mCPBA H2SO4 DMSO...
..) Complete the following transformation using some of the reagents provided below. Show each step of the synthesis and the reagents needed. For extra credit: H+ (cat) HT/H20 Os04 (CH3)2CO CH3CH2Br мСРВА HO-(cat) H2/Pd/lindlar HgSO4 BH3 HOCH2CH2OH Br2 Na/NH3 nBuli KMnO4 NaNH2 CH3(CH2)2CHO Mg/Et20 OH
Complete the following synthesis by selecting from the list of 10 reagents below. Each reagent (or set of reagents) is labeled as a letter. In the answer box, simply place the order of reagents used as uppercase letters. For example, if your synthesis involves using reagent A followed by B,followed by C, and then D, your answer would be: ABCD H2SO4 TMS-CI PCC 2. H20 pyridine PBr3 H2CrO4 TBAF 1. NaH H'/H2O 2. H20 2. CHl Enter Your Answer:
2) Multistep syntheses. Starting from the indicated reactant, and using ONLY the reagents below, outline a synthesis for cach requested product. IN ALL CASES. draw the structure of the product of EACH step, giving the number of the reagent needed to prepare that product from its precursor and.. i) İİ) draw the structure of the final product Cl2 Br HNO3 R-CI 2 R CH34 1) KMno, Hos 2) H30 workup R CH3CH2CH210 な-11 R (CH3)3C-12 HCl 19 13 Br2/hv or...
Using benzene as the only organic starting material, design a synthesis(no mechanism) for the following (use any other reagents that you need). Please disregard the orange box that is in the structure. Na
Integrated Problem 09.64 Using acetylene and methyl bromide as your only sources of carbon atoms, propose a synthesis for the following compound: + En A Choose from the following list of reagents (A-H): 1) Br2 2) Excess H20 3) NaNH2 1) H2, Lindlar's catalyst 2) HBr 1) NaNH2 2) EtBr 3) Na, NH3 (1) 4) MeBr 1) NaNH2 2) EtBr 3) NaNH2 4) MeBr H 1) Na, NH3 (1) 2) MCPBA 1) NaNH2 2) EtBr 3) H2, Pt 1) H2,...
9. (7) Write a complete multi-step synthetic route for the following transformations, using only the given starting material(s) as the sole source(s) of carbon. You do not have to show the synthesis of solvents or reagents if they are not incorporated into the final product. Clearly (in) Show all intermediate steps and reagents, but do not show any mechanisms or transition states. (24 points): a) Y. I-oyar onbino - we
stepwise synthesis for N-propylbutanamide using 1-propanol and/or carbon dioxide as your only source of carbon Use Using the reagents below, list in order (by letter, no period) those necessary to provide this synthesis. Note: Not all spaces provided may be needed. Hints: First receive a Grignard reagent in steps 1 and 2. Use propanol in step 5. In step 9 a product from step 4 reacts with a product from step 8. a. NH3 b. Mg/ether c. SOCl2 d. 1....
Propose a synthesis of the following derivative of diethyl malonate using reagents from the choices provided below. (From the choices provided, list the reagent(s) in order that will accomplish this transformation. No more than 4 steps are required. List your answer as a single letter (single-step transformation) or a series of letters (multi-step transformation) with no commas separating them.) Reagents available a. Eto Na g. CH2=CHCH=CHCH,Br b. CH3 CH2Br c. CH3 CH, CH, CH(CH3)Br d. (CH3)2 CHCH, CH,Br e. CH3...
Practice Problem 23.50 Starting with cyclopentene and using any other reagents of your choice, show how you would make each of the following compounds: (a) (b) (c) HO OH Choose from the following list of reagents: c b d Pd[OAC)2, PPhy, BN NaOH, H20, heat H,0NaOH (xs) CH2CH2 f g e BHy-THF (xs) CHşlyZn-Cu. Et, BCOM) h Grubbs catalyst i k - BE Be Using the reagents above, list in order (by letter, no period) those necessary to provide each...
X Incorrect. The synthesis above used bromobutane, but acetylene is the only allowed source of carbon atoms. Using the reagents given, identify a synthetic route for the production of bromobutane from acetylene. ? H Br The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide...