Question

(#2) Draw the structure of the major organic mono-substituted product. Draw all bonds except C-H. Draw all lone pairs. (~15Pts) (a) O'Bu O'Bu Cla. FeCla (b) CF3 CF3 CH,сосI AICI (c) OCH3 осн, HNO3, H2SO4 Н,с Нас CH3 CH3 (d) Br Br Me N Me N So3 В H2SO4 Bг CN CN (e) NH3CI NH3CI HNO3, H2SO4

Answer 1

CH? crt3 cl2lFecl? otBu is op director. But it is Bulky group : It directs Electrophile (10 to para rather than of Tho. C-E El Chococh Alch Meta All Electyl meta CF is strong sing deactivator and meta director. & Direct CH ) Electrophile to meta OCH © as a Hot 4 Nitration Oct is strong acfiratar Than CH3. och direct Electrophile of of the cor) para But para s blocked e of the product is predominant

@ Sulfonation para & BY NCH3)2 S3, Hy sour çuş Br: BV EN AC. I i Brit I . Can: : 20- men > Br J CN Strong activatal of para cor or the to directs wme), PH DNtz ei H3, 1125 meta Nitratan Witz e ding deactivector and meta director