Consider translational motion of single molecule (mass = 5.314 * 10-26 kg) trapped in one-dimensional box potential ("particle in a box), which has a width of 5 cm.
A) What is the energy difference between the two lowest quantized energy levels?
B) The amount of classical translational thermal energy for a molecule confined in one dimension is 1/2kT where T is the temperature and k is the Boltzmann constant (1.381 * 10-23 J/K). If the temperature is 300 K, at what value of n would the quantized energy exceen the thermal energy?
C) Using the vaue of n from b), calculate the energy seperation between the adjacent levels (ie, n vs n+1)
Consider translational motion of single molecule (mass = 5.314 * 10-26 kg) trapped in one-dimensional box...
Calculate the probability of exciting an electron in a one-dimensional box (actually a nanoscale wire) to the n 2 excited state if the box is 10.0 nm long and the temperature is 410.0 K. For the one- dimensional box, En = n2t2h2/(2ma2) and the levels are non-degenerate (but remember that the energy should be measured relative to the ground state). For this example, T2h/(2mea2) is equal to 1.381- 10 23 JK-1 J and the partition function is 2.44. kB 6.02-10-22...
2. (a) When a particle of mass 1.0 x 10-26 g in a one-dimensional box goes from the n=3 level to n=1 level, it emits a radiation with frequency 5.0 x 1014 Hz. Calculate the length of the box. (b) Suppose that an electron freely moves around inside of a three-dimensional rectangular box with dimensions of 0.4 nm (width), 0.4 nm (length), and 0.5 nm (height). Calculate the frequency of the radiation that the electron would absorb during its transition...
Please answer below question (A-C). Thank you 3 attempts lett Check my work te the difference in energy between the n -2 and n-1 states of an electron in a one- (a) Calcula dimensional box with a length of 0.50 nm. x 10.J (b) Caleulate the difference in energy between the n - 2 and n -1 states for an oxygen molecule in a one-dimensional box with a length of 10 cm x 10J (c) What do the different values...
Please explain the steps energies o P Q10M.2 Consider a nitrogen (N2) molecule bouncing around a box 10 cm on a side. Pretend that the molecule can only move in one dimension. Note that the mass of an N2 mol- ecule is roughly 28 times that of a proton. (a) What is the approximate value of n for the molecules energy eigenfunction if it has an energy E0.025 eV that one would expect from random thermal motion? (b) Estimate the...
Solve the LAST ONE INCLUDE ALL THE STEPS The force constant for the carbon monoxide molecule is 1,908 N m At 1,000 K what is the probability that the molecule will be found in the lowest excited state? At a given temperature the rotational states of molecules are distributed according to the Boltzmann distribution. Of the hydrogen molecules in the ground state estimate the ratio of the number in the ground rotational state to the number in the first excited...
Q10M.9 Consider an HCl molecule. The hydrogen atom irn this molecule has a mass we can look up (see the inside front cover), and the chlorine mass is enough larger that we can (to a first degree of approximation) consider it to be fixed. The bond between these atoms has a local minimum .13 nm, and for "small oscillations" around that minimum, the bond's potential energy can be modeled as a harmonic oscillator potential energy function. Suppose we find that...