Given the Cosey, HSQC and HMBC experiments assign the 1H NMR spectrum and 13C NMR spectrum signals of the compound. 1H peaks are labelled using lowercase letters and 13C peaks using uppercase. Be aware that the letters of the same peak does not necessarily refer to the position in the molecule. For example, peak a in the 1H and peak A in the 13C NMR are not necessarily assigned to the same number atom. The assignment of protons 4 and 6 is already given.
H Spectra
C13 Spectra
Homework Answers
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Given the Cosey, HSQC and HMBC experiments assign the
1H NMR spectrum and 13C NMR spectrum...
for the following 2 compounds, please calculate, and show the calculations for, the degree of unsaturation, assign the IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR peaks, and draw th...
for the following 2 compounds, please calculate, and
show the calculations for, the degree of unsaturation, assign the
IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR
peaks, and draw the structure for the unknown compound.
CHIM 245 Spectroscopy Problem Set #2 In this problem set there are two unknown compounds. You are provided with the formula, IR spectrum, "C NMR spectrum, and 'H NMR spectrum for each compound. Each unknown is worth 10 points, with an...
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a st...
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 148, an IR peak at 1680 cm'and gives the following H and 13C NMR spectra 3H зн 2H 2H 2H 3 5 2 7 6 4 PPM 160 140 180 60 220 200 20 0 120 100 80 40 PPM -
On the attached image are 1H NMR, 13C NMR, and IR spectra of a compound with...
On the attached image are 1H NMR, 13C NMR, and IR
spectra of a compound with the formula C4H8O. 1H NMR signal at 1.2
is caused by 3 hydrogens, the sigbal at 2.1 is caused by 3
hydrogens, and the signal at 2.5 is caused by 2 hydrogens. Identify
the compound.
CH 1110 9 8 7 6?4 Problem 6. 'H NMR spectrum of compound HsO Problem 6. 13C NMR spectrum of compound C4HsO 200 180 160 140 120 100 80...
28. A compound with the molecular formula of C3H.ON shows 1H NMR and 13C NMR as...
28. A compound with the molecular formula of C3H.ON shows 1H NMR and 13C NMR as below. Give the most plausible structure in the box. 2H, 3 peaks 2H, 3 peaks 1H, 1 peak PPM 180 160 140 120 100 80 60 40 20 PPM
Create OscerSkotch Answer 6 Th e 1H-NMR and 13C-NMR spectra of an unknown compound s (formula...
Create OscerSkotch Answer 6 Th e 1H-NMR and 13C-NMR spectra of an unknown compound s (formula CoMzo) are shown below. Draw the structure of B. The total integration of the peaks at around 7 ppm is 4. The integration of the peak at around 2 ppm is 6 ppm 200 180 160 140 120 100 060 4020
1H NMR Spectra: 1H NMR Spectra (Zoomed in): Through the use of the given spectral data,...
1H NMR Spectra:
1H NMR Spectra (Zoomed in):
Through the use of the given spectral data, deduce the structure of the molecule, showing all reasoning in the process. Note that the peaks at 3.7, 4.2, and 7.27 ppm don't belong to the compound; explain what these peaks correspond to: Formula: CH10 13C NMR & DEPT-135: 13C NMR (ppm) Dept-135 57 + + | + + 58 109 111 127 131 149 153 190 No peak No peak No peak +...
The 1H-NMR and 13C-NMR spectra of an unknown compound (formula C8H10) are shown below. Draw the structure of the unknown...
The 1H-NMR and 13C-NMR spectra of an unknown compound (formula
C8H10) are shown below. Draw the structure of the unknown compound.
The total integration of the peaks at around 7 ppm is 4. The
integration of the peak at around 2 ppm is 6.
7 6 5 4 3 ppm TTTTTTTTTTTTTTTT 200 180 160 140 120 100 80 60 40 20 0 pom CH3 Create OscerSketch Answer 8 Incorrect: Answer has an incorrect structure.
Which compound gives the following spectra? For the 1H-NMR assign all signals. interpret mol peak and...
Which compound gives the following spectra?
For the 1H-NMR assign all signals. interpret mol peak and base peak
in the mass spectrum if a mole peak exists. Assign at least two 13C
signals. How does the IR spectrum support your finding?
Check 200 180 160 120 80 60 40 20 0 140 a 100 ppm s, 3H t, 3 H d. 2 a. 2 H d. 2H s, 1 H 1 10 9 8 7 6 4 3 2 1...
Assign as many peaks as possible in the IR, 1H NMR, and 13C NMR spectra. The...
Assign as many peaks as possible in the IR, 1H NMR,
and 13C NMR spectra. The spectra are for
triphenylmethanol.
Please show work for better understanding 13.9 Define coupling constant. The distance between different signals The...
Please show work for better understanding 13.9 Define coupling constant. The distance between different signals The distance between the peaks of a multiplet The distance between the signal and the reference The distance between the first signal and the last signal 13.20 Where do N–H signals appear 1H NMR spectrum 13C NMR spectrum 1H and 13C NMR spectra 1H, 13C, and DEPT spectra 13.17 Give the use of Distortionless Enhanced Polarization Transfer (DEPT). a) Gives correlations between an 1H NMR...
for the following 2 compounds, please calculate, and
show the calculations for, the degree of unsaturation, assign the
IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR
peaks, and draw the structure for the unknown compound.
CHIM 245 Spectroscopy Problem Set #2 In this problem set there are two unknown compounds. You are provided with the formula, IR spectrum, "C NMR spectrum, and 'H NMR spectrum for each compound. Each unknown is worth 10 points, with an...
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 148, an IR peak at 1680 cm'and gives the following H and 13C NMR spectra 3H зн 2H 2H 2H 3 5 2 7 6 4 PPM 160 140 180 60 220 200 20 0 120 100 80 40 PPM -
On the attached image are 1H NMR, 13C NMR, and IR
spectra of a compound with the formula C4H8O. 1H NMR signal at 1.2
is caused by 3 hydrogens, the sigbal at 2.1 is caused by 3
hydrogens, and the signal at 2.5 is caused by 2 hydrogens. Identify
the compound.
CH 1110 9 8 7 6?4 Problem 6. 'H NMR spectrum of compound HsO Problem 6. 13C NMR spectrum of compound C4HsO 200 180 160 140 120 100 80...
28. A compound with the molecular formula of C3H.ON shows 1H NMR and 13C NMR as below. Give the most plausible structure in the box. 2H, 3 peaks 2H, 3 peaks 1H, 1 peak PPM 180 160 140 120 100 80 60 40 20 PPM
Create OscerSkotch Answer 6 Th e 1H-NMR and 13C-NMR spectra of an unknown compound s (formula CoMzo) are shown below. Draw the structure of B. The total integration of the peaks at around 7 ppm is 4. The integration of the peak at around 2 ppm is 6 ppm 200 180 160 140 120 100 060 4020
1H NMR Spectra:
1H NMR Spectra (Zoomed in):
Through the use of the given spectral data, deduce the structure of the molecule, showing all reasoning in the process. Note that the peaks at 3.7, 4.2, and 7.27 ppm don't belong to the compound; explain what these peaks correspond to: Formula: CH10 13C NMR & DEPT-135: 13C NMR (ppm) Dept-135 57 + + | + + 58 109 111 127 131 149 153 190 No peak No peak No peak +...
The 1H-NMR and 13C-NMR spectra of an unknown compound (formula
C8H10) are shown below. Draw the structure of the unknown compound.
The total integration of the peaks at around 7 ppm is 4. The
integration of the peak at around 2 ppm is 6.
7 6 5 4 3 ppm TTTTTTTTTTTTTTTT 200 180 160 140 120 100 80 60 40 20 0 pom CH3 Create OscerSketch Answer 8 Incorrect: Answer has an incorrect structure.
Which compound gives the following spectra?
For the 1H-NMR assign all signals. interpret mol peak and base peak
in the mass spectrum if a mole peak exists. Assign at least two 13C
signals. How does the IR spectrum support your finding?
Check 200 180 160 120 80 60 40 20 0 140 a 100 ppm s, 3H t, 3 H d. 2 a. 2 H d. 2H s, 1 H 1 10 9 8 7 6 4 3 2 1...
Assign as many peaks as possible in the IR, 1H NMR,
and 13C NMR spectra. The spectra are for
triphenylmethanol.
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