Use standard free energy of formation data to calculate the standard free energy change of reaction, ΔGr0, and the equilibrium constant (molar scale) at 25oC and I = 0 for each of the following reactions:
(a) Fe3+ + 6 CN- = Fe(CN)63-
(b) Mg2+ + 2 OH- = Mg(OH)20
(c) Mg2+ + 2 OH- = Mg(OH)2(s)
(d) Al3+ + F- = AlF2-
Some supplementary G0f data (all in kJ/mol): CN-, 172.4; Fe(CN)63-, 729.4, AlF2-, -808.2
Use standard free energy of formation data to calculate the standard free energy change of reaction,...
Calculate the standard free-energy change at 25 ∘C for the following reaction: Mg2+(aq) + Zn(s) → Mg(s) + Zn2+(aq) Express your answer to three significant figures and in units of kJ/mol. Consider constructing a voltaic cell with one compartment containing a Zn(s) electrode immersed in a Zn2+ aqueous solution and the other compartment containing an Al(s) electrode immersed in an Al3+ aqueous solution. What is the spontaneous reaction in this cell? Group of answer choices Zn + Al3+ → Al...
Calculate the standard change in Gibbs free energy for the reaction at 25 °C. Standard Gibbs free energy of formation values can be found in this table. 6 C1,() +2 Fe,0,(s) 4 FeC1, (s) + 30,() AGE kJ/mol
Calculate the standard change in Gibbs free energy for the reaction at 25 °C. Standard Gibbs free energy of formation values can be found in this table. 3H2(g) + Fe,0,($) 2Fe(s) + 3 H,0 () AGran kJ/mol
Calculate the standard change in Gibbs free energy for the reaction at 25 °C. Refer to the AGⓇ values. 3 H2(g) + Fe, 0,(s) 2 Fe(s) + 3 H2O(g) AG" Calculate the standard change in Gibbs free energy for the reaction at 25 °C. Standard Gibbs free energy of formation values can be found in this table. C,H,(8) +4 C1,() 2 CCI, (1) + H2(g) AGE. kJ/mol
Calculate the standard change in Gibbs free energy, AGixn , for the given reaction at 25.0 °C. Consult the table of thermodynamic properties for standard Gibbs free energy of formation values. NH,CI() = NH(aq) + Cl(aq) AGxn = -7.7 kJ/mol Determine the concentration of NH(aq) if the change in Gibbs free energy, AGrxn , for the reaction is –9.53 kJ/mol. [NH] = 0.72 Consider a general reaction enzyme A(aq) = B(aq) The AG® of the reaction is -4.880 kJ mol-....
12. Use the data in problem 11 to calculate the standard free energy, DGº, for the reaction below. cell celi Mg(s) + Pb3* (aq) ® Mg?* (aq) + Pb(s) DG = -217000 J = - 243000 = - 434000 DG = +243000 J (6) DG (c) DG cell cell 13. Obtain the equilibrium constant Ke at 25°C from the free-energy change for the reaction Fe(s) + Cult (94) Feuq) + Cut)
Use standard reduction potentials to calculate the standard free energy change in kJ for the reaction: Fe3+(aq) + Cr2+(aq) Fe2+(aq) + Cr3+(aq) Answer: kJ K for this reaction would be than one.
Calculate the standard free energy change for the combustion of one mole of methane using the values for standard free energies of formation of the products and reactants. The sign of the standard free energy change allows chemists to predict if the reaction is spontaneous or not under standard conditions and whether it is product-favored or reactant-favored at equilibrium. kJ/ mol-rxn
Calculate the standard change in Gibbs free energy, ΔG'm, for the following reaction at 25.0 ℃ Standard Gibbs free energy of formation values can be found here. NH,CI(s) 근 NH, (aq) + Cl (aq) Number k.J/mol Then, determine the concentration of NH4 (aq) if the change in Gibbs free energy, AGrxn, for the reaction is-9.53 kJ/mol. Number
Calculate the equilibrium constant from the standard free energy change. Using standard thermodynamic data (linked), calculate the equilibrium constant at 298.15 K for the following reaction 2502(g) + O2(0) 2503(9) AH°F (kJ/mol) AGⓇ, (kJ/mol sº (/mol K) 205.1 Oxygen 02(0) (9) O3(9) 249.2 231.7 161.1 142.7 163.2 238.9 AH°: (kJ/mol Agºr (kJ/mol) 5° (J/mol K) 31.8 0.3 0.3 278.8 3 3.0 167.8 33.0 - 15.0 Sulfur S(s, rhombic) S(s, monodinic) S(g) Sz"(aq) Sg(9) SzCl2(g) SF6(9) H2S(9) soz(9) SO3(0) 1 0....