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For the generic reaction shown, K-0 reaction mixture for which O-0.205 at 950 K .355 (at...
Chapter 18 Thermodynamics Homework 1.Predict the sign of AS for each process: a) The boiling of water b)2HgO(s)-2Hg(I) + 02(s) c) CaCO, (s)CaO(s)+ CO (g) 2. Is the following process spontaneous or nonspontaneous at a given temperature? NaNO,(s) ->NaNO,(aq) 3. If a reaction has ΔS < 0 and ΔΗ < 0 will the reaction always be spontaneous, spontaneous at low T, spontaneous at high T, or never spontaneous? 4.Consider this reaction: Calculate ΔG at 25 °C and determine whether the...
When ΔG ̊=0, the system is at equilibrium and both the forward and reverse reaction are proceeding at equal rates. This is the case during phase transitions. Consider the phase transition and the data shown for BCl3 below. Calculate the boiling point (in ̊C) for BCl3. BCl3(l) ⇄ BCl3(g) Hf ̊ (kJ/mole) S ̊ (J/mol∙K) BCl3(l) -418 209 BCl3(g) -395 290 4. When AG°=0, the system is at equilibrium and both the forward and reverse reaction are proceeding at equal...
0.0455 O 0.0330 QUESTION 8 Consider the reaction shown below. AH is positive for the reaction. 4CuO (s) + CH4 (9) CO2(g) + 4Cu (s) + 2H20 (9) State whether each change will cause the reaction to shift to the left, to the right, or no change. Enter the words "left","right" or "no change (without the quotation marks) into each blank. A coldfinger is added to condense out water vapor (H20 (g)) in the reaction mixture. The partial pressure of...
30) At constant pressure and temperature, which statement is true? A) All reactions for which k < 1 are spontaneous B) All reactions for which AG are spontaneous C) All reactions for which AH<0 are spontaneous. D) All reactions for which AS <0 are spontaneous 11) 11) Consider the galvanic cell, Pb(s) IP20) Cu2+(a) Cu(s). Which one of the following changes to the cell would cause the cell potential to increase (ie, become more positive)? A) increase the mass of...
1) At 298 K, an equilibrium mixture contains P H2=0.958 atm, P I2= 0.877 atm and P HI=0.020 atm. Please try and answer all! You must show all your work to receive credit. Watch sig figs! Consider the reaction: 1) At 298 K, an equilibrium mixture contains P H2-0.958 atm, P ½=0.877 atm, and P HI-0.020 atm. Calculate the value of the equilibrium constant Kp? a) (o, o2) 0.938x o.87? b) And what is the value of the equilibrium constant...
QUESTION 2 The reaction illustrated by the graph shown would be considered and have a ---- G products free energy amount of energy required reactants course of reaction Exergonic, negative Exergonic, positive Endergonic, negative Endergonic, positive At equilibrium zero change QUESTION 3 Which of the following statements about enzymes is FALSE? Only proteins are enzymes and can perform catalytic reactions, Enzymes act to lower the activation energy of a reaction Enzymes can speed up the rate of a reaction Enzymes...
5. Consider the generic reaction shown below in which reactant A is converted to product B. A pure sample of reactant A is allowed to reach equilibrium. The concentrations of both A and B were monitored during this process and plotted below as a function of time. A(8)=B (8) concentration time a. Based on these data, is the value of Key for this reaction greater than or less than 1? Briefly explain how you can tell. b. The reaction is...
Can anyone make me explain 1 and 2. I am confused whether they are true or false. 16. A plot of free energy vs. reaction progress is shown below for the reaction Ag) + B(8) C(g) Free energy 100% 100% A(g) & B(g) Reaction C(g) - progress How many of the statements (i-v) are true? i. The minimum energy corresponds to the mixture of reactants and products present at equilibrium. ii. At equilibrium, all of A and B have røacted...
1. True or False: a) A reaction is spontaneous if ΔSnn > 0. b) The Fourth Law of Thermodynamics states: The entropy of a pure, perfect crystal at O K is. c) For A(g) + B(g) D(g) + E(g), if ΔΗ'm < 0 and Δ5%n > 0, the reaction is spontaneous regardless of temperature. d) For A(g) + B(g) → D(g) + E(g), ifAH"m > 0 and Δ5%n < 0, it will be possible to find a temperature above which...
question 5 CHEM 130 Group-study Worksheet 9 5. Consider the generic reaction shown below in which reactant A is converted to product B. A pure sample of reactant A is allowed to reach equilibrium. The concentrations of both A and B were monitored during this process and plotted below as a function of time. A(8)=B (B) concentration time a. Based on these data, is the value of Key for this reaction greater than or less than 1? Briefly explain how...