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A. Standardization of Sodium Hydroxide Solution Table 13.1 (data) Sample 1 Sample 2 Sample 3 Mass of container plus sample Ma

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The titration is used to obtain the concentration of a solution from the concentration of another known solution (standard solution). Thus, knowing the volume of both solutions (standard solution and problem solution) and the concentration of the standard solution, it is possible to know the concentration of the problem solution. In this case, sodium hydroxide is a difficult base to obtain in pure form because it tends to absorb water from the air and its solutions react with carbon dioxide. In this way, to know its concentration, it was titrated with potassium phthalate, which is an acid of known concentration. In this way the reaction that was carried out was a neutralization because an acid and a base reacted:

KHC8H4O4 + NaOH \rightarrow KNaC8H4O4 + H2O

acid base salt water

Sample 1 Sample 2
Mass of KHP tritated 0.2991 g 0.4118 g
Moles of KHP titrated 0.00146 mol 0.00202 mol
Moles of NaOH required in titration 0.00146 mol 0.00202 mol
Volume of NaOH used in titration 15.80 mL 17.70 mL
Calculated NaOH molarity 0.0924 mol/L 0.1141 mol/L
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