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Thermodynamics
6.2. Multiple components (1.5 pt) Assume we have a reaction with the following stoichiometry In...
For a hypothetical chemical reaction that has the stoichiometry 2X + Y -----Z the following initial...
For a hypothetical chemical reaction that has the stoichiometry 2X + Y -----Z the following initial data were obtained X (Mol/L Y(Mol/L) rate of formation of Z (Mol/L s .4 .2 1.4 x 10^-3 .4 .4 2.8 x 10^-3 .2 .1 7.0 x 10^-4 .6 .6 4.2 x 10^-3 Give rate Law for this reaction Callculate rate constant and specify units How long must reaction proceed to produce concentration of Z =to .2 molar if initial concentrations of x=.8M and...
Question 2 For an isothermal, constant volume batch reactor in which the following reaction is occurring...
Question 2 For an isothermal, constant volume batch reactor in which the following reaction is occurring A - B A laboratory technician measures the rate of reaction of A in a reactor for different concentrations, and obtains the following data: CA 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 1.0 [mol.L' -TA 0.1 0.4 0.9 1.6 2.5 3.6 4.9 6.4 10 (mol.L-min'] The laboratory technician tells you that if you plot - r against (CA) that you get a straight...
1) The following experimental data were obtained for a particular irreversible reaction at T = 25.0...
1) The following experimental data were obtained for a particular irreversible reaction at T = 25.0 °C. It is assumed that the reaction obeys a rate law of the form rate = - d[A]/dt = k [A]P [B]" (1.1) Trial [A]initial (mol/L) [B]initial (mol/L) (Rate) initial (mol/L•min) 0.00100 0.00100 0.00100 0.00100 0.00100 0.00200 0.00400 0.01000 2.6 x 10-8 1.2 x 10-7 3.9 x 10-7 2.4 x 10-6 0.00200 0.00400 0.01000 0.00200 0.00200 0.00200 1.5 x 10-7 1.1 x 107 1.6...
7. What is the reaction order for each reactant and the rate coefficient for the following...
7. What is the reaction order for each reactant and the rate coefficient for the following reaction? A+B+C ->Z [A] (mol L B (mol L[C] (mol L ](mol L sec1) 0.010 0.020 0.010 0.020 0.0100 0.0100 0.0200 0.0100 0.10 0.10 0.10 0.20 3.0 x 10-2 3.0 x 102 1.2 x 10-1 1.5 x 10-2
1. The kinetics of the following reaction have been studied: N2 + 3 H2 → 2...
1. The kinetics of the following reaction have been studied: N2
+ 3 H2 → 2 NH3 The rate of of appearance of NH3 was measured as
∆[NH3]/∆t = 9.00 x 10-2 mol L-1 s-1
(a) What is the rate of the reaction in mol L-1 s-1?
(b) What is ∆[N2]/∆t in mol L-1 s-1?
(c) What is ∆[H2]/∆t in mol L-1 s-1?
2. The initial rate of the reaction of species A and B A + 2 B →...
Please answer all, I rate, thank you. THE IODINE CLOCK- REACTION KINETICS EXPERIMENT 3 PRE-LABORATORY QUESTIONS...
Please answer all, I rate, thank you.
THE IODINE CLOCK- REACTION KINETICS EXPERIMENT 3 PRE-LABORATORY QUESTIONS (WEEK 1) Fully answer these questions in your laboratory notebook before coming to lab. Show all work for numerical calculations. 1. If the rate law for a reaction is Rate [A][B What is the overall order of the reaction? a. b. If the concentration of A is doubled and the concentration of B is tripled, how will this affect the rate of the reaction?...
Consider the reaction: 2 NO(g) + O2 (g)--> 2 NO2 (g) The following data were obtained...
Consider the reaction: 2 NO(g) + O2 (g)--> 2 NO2 (g)
The following data were obtained from three experiments using
the method of initial rates:
3. Consider the reaction: 2 NO(g) + O2(g) → 2 NO2(g) The following data were obtained from three experiments using the method of initial rates: Initial [NO] Initial rate NO Initial [02] mol mol L-1 mol L-1 L-15-1 0.010 0.010 Experiment 1 Experiment 2 Experiment 3 0.020 0.010 2.5 x 10-5 1.0 x 10-4 5.0...
The kinetics of the following reaction have been studied: 4 NO + O2 → 2 N2O3...
The kinetics of the following reaction have been studied: 4 NO + O2 → 2 N2O3 The rate of appearance of N2O3 was measured as ∆[N2O3]/∆t = 9.00 x 10-2 mol L-1 s-1 (a) What is the rate of the reaction in mol L-1 s-1? (b) What is ∆[NO]/∆t in mol L-1 s-1? (c) What is ∆[O2]/∆t in mol L-1 s-1?
Homework 8-3_1 Reaction Rate Orders, Temp Effects Reaction Rates and Rate Orders The following initial rate...
Homework 8-3_1 Reaction Rate Orders, Temp Effects Reaction Rates and Rate Orders The following initial rate data was collected for the reaction: HI(g) + CHşl(g) à CH.(g) +1-(9) Experiment (HI) (CHI) Initial Rate 0.015 M0.900 M 4.01 x 10M's 0.030 M0.900 M 8.04 x 10'Ms 0.030 M0.450 M 3.99 x 10 m/s 1. What is the rate law for this reaction? a. Rate =k [HI] [CHI] b. Rate = k [HI] [C,H,I] c. Rate = k [HI] (C,H,I] d. Rate...
Problem #3 (20 marks) The following kinetic data (initial rates) were obtained for the reaction 2...
Problem #3 (20 marks) The following kinetic data (initial rates) were obtained for the reaction 2 ICI(g) + H2(g) → 12(g) + 2 HCI (9) Experiment [Cl]. (mmol/L) [Hz]. (mmol/L) V. (mol/L s) 3.0 3.0 14.8 X10-7 3.0 1.8 8.9 x10-7 1.5 1.8 4.44 x 10-7 3.7 1.3 ? (a) Write the rate law for the reaction (b) From the data, determine the value of the rate constant (c) Use the data to predict the reaction rate for experiment 4.
Question 2 For an isothermal, constant volume batch reactor in which the following reaction is occurring A - B A laboratory technician measures the rate of reaction of A in a reactor for different concentrations, and obtains the following data: CA 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 1.0 [mol.L' -TA 0.1 0.4 0.9 1.6 2.5 3.6 4.9 6.4 10 (mol.L-min'] The laboratory technician tells you that if you plot - r against (CA) that you get a straight...
1) The following experimental data were obtained for a particular irreversible reaction at T = 25.0 °C. It is assumed that the reaction obeys a rate law of the form rate = - d[A]/dt = k [A]P [B]" (1.1) Trial [A]initial (mol/L) [B]initial (mol/L) (Rate) initial (mol/L•min) 0.00100 0.00100 0.00100 0.00100 0.00100 0.00200 0.00400 0.01000 2.6 x 10-8 1.2 x 10-7 3.9 x 10-7 2.4 x 10-6 0.00200 0.00400 0.01000 0.00200 0.00200 0.00200 1.5 x 10-7 1.1 x 107 1.6...
7. What is the reaction order for each reactant and the rate coefficient for the following reaction? A+B+C ->Z [A] (mol L B (mol L[C] (mol L ](mol L sec1) 0.010 0.020 0.010 0.020 0.0100 0.0100 0.0200 0.0100 0.10 0.10 0.10 0.20 3.0 x 10-2 3.0 x 102 1.2 x 10-1 1.5 x 10-2
1. The kinetics of the following reaction have been studied: N2
+ 3 H2 → 2 NH3 The rate of of appearance of NH3 was measured as
∆[NH3]/∆t = 9.00 x 10-2 mol L-1 s-1
(a) What is the rate of the reaction in mol L-1 s-1?
(b) What is ∆[N2]/∆t in mol L-1 s-1?
(c) What is ∆[H2]/∆t in mol L-1 s-1?
2. The initial rate of the reaction of species A and B A + 2 B →...
Please answer all, I rate, thank you.
THE IODINE CLOCK- REACTION KINETICS EXPERIMENT 3 PRE-LABORATORY QUESTIONS (WEEK 1) Fully answer these questions in your laboratory notebook before coming to lab. Show all work for numerical calculations. 1. If the rate law for a reaction is Rate [A][B What is the overall order of the reaction? a. b. If the concentration of A is doubled and the concentration of B is tripled, how will this affect the rate of the reaction?...
Consider the reaction: 2 NO(g) + O2 (g)--> 2 NO2 (g)
The following data were obtained from three experiments using
the method of initial rates:
3. Consider the reaction: 2 NO(g) + O2(g) → 2 NO2(g) The following data were obtained from three experiments using the method of initial rates: Initial [NO] Initial rate NO Initial [02] mol mol L-1 mol L-1 L-15-1 0.010 0.010 Experiment 1 Experiment 2 Experiment 3 0.020 0.010 2.5 x 10-5 1.0 x 10-4 5.0...
Homework 8-3_1 Reaction Rate Orders, Temp Effects Reaction Rates and Rate Orders The following initial rate data was collected for the reaction: HI(g) + CHşl(g) à CH.(g) +1-(9) Experiment (HI) (CHI) Initial Rate 0.015 M0.900 M 4.01 x 10M's 0.030 M0.900 M 8.04 x 10'Ms 0.030 M0.450 M 3.99 x 10 m/s 1. What is the rate law for this reaction? a. Rate =k [HI] [CHI] b. Rate = k [HI] [C,H,I] c. Rate = k [HI] (C,H,I] d. Rate...
Problem #3 (20 marks) The following kinetic data (initial rates) were obtained for the reaction 2 ICI(g) + H2(g) → 12(g) + 2 HCI (9) Experiment [Cl]. (mmol/L) [Hz]. (mmol/L) V. (mol/L s) 3.0 3.0 14.8 X10-7 3.0 1.8 8.9 x10-7 1.5 1.8 4.44 x 10-7 3.7 1.3 ? (a) Write the rate law for the reaction (b) From the data, determine the value of the rate constant (c) Use the data to predict the reaction rate for experiment 4.
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