1. Why is there an ease of nitration and bromination of phenol relative to benzene?
2. What are some reactions of alcohols: - oxidation, dehydration, esterification, acylation.
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1. Why is there an ease of nitration and bromination of phenol relative to benzene? 2....
N III IV V 4. Everyone must write and post the reactions of benzene (chlorination, bromination, nitration, sulfonation, Friedel Crafts Alkylation and Acylation) I= 1 1 1 ires Cyclize 2 not planar, 3) Cong xe) allcarn attalno b) xes spe Yes enta. 4 4 obey the so this not aromate Y > n. 2 some say not
Show how you would synthesize each compound from benzene, toluene, or phenol using the following reactions: Reactions 1. Halogenation 2. Nitration 3. Sulfonation 4. Friedel-Crafts acylation 5. Friedel-Crafts alkylation 6. Oxidation of methyl group 7. Reduction of nitro group • Choose the starting material from the drop-down list • Enter the number(s) of the desired reactions in the order that you wish to use them without commas between • If a reaction is used more than once, enter its number...
1. What is the IUPAC name for the following compound? N 2. Which one of the following compound is aromatic? 3. Which one of the following compound is nonaromatic? IV 4Everyone must write and post the reactions of benzene (chlorination, bromination nitration, sulfonation, Fredel Crafts Alkylation and Acylation)
Nitration of Methylbenzoate. Lab 1 6. Why is it important to maintain the reaction temperature low and the addition of nitric acid-sulfuric acid mixture carried out slowly? 8. Which ring of phenyl benzoate would you expect to undergo nitration more easily? Explain. 9. Which is nitrated faster, toluene or phenol? Explain. phenol or nitrobenzene methyl benzoate or phenol nitrobenzene or methyl benzoate benzene or toluene 10. Show all mono, di and trinitration products of toluene. Do you think the mononitration...
1. why is toluene a stronger nucleophile than benzene? 2.why is phenol a stronger nucleophile than benzene?
1. why is toluene a stronger nucleophile than benzene? 2.why is phenol a stronger nucleophile than benzene?
Electrophilic bromination of an equimolar mixture of methylbenzene (toluene) and (trifluoromethyl)benzene with one equivalent of bromine gives exclusively 1-bromo-2-methylbenzene and 1-bromo-4-methylbenzene. Explain why none of the (trifluoromethyl)benzene reacts Explain the regiochemical outcome of the reaction In other words, why are 1-bromo-2-methylbenzene and 1-bromo-4-methylbenzene formed from the toluene? Electrophilic nitration of benzoic acid gives almost exclusively 1,3-nitrobenzoic acid. By drawing the appropriate resonance forms of the intermediate cations resulting from attack of [NO2]+, explain this result.
Post Lab Questions for Nitration of Acetanilide, Nitration of Methyl Benzoate, Nitration of Phenylacetonitrile, Nitration of Phenol. 1. What product(s) do you expect to be formed in the nitration of phenol? Why? 2. All three of the nitrophenols have boiling points well above 200°C. Explain clearly why it was possible to distill something with such a high boiling point when the temperature of the distillate never rose much above 100°C. 3. What product did you actually obtain in the distillate?...
What are the chemical equation for these reactions: 1) sulfonation of toluene 2)permanganate oxidation of isobutylbenzene 3)nitration of anisole 4) bromination of aniline 5)blue light-catalyzed bromination of sec-butylbenzene 6)hydration of acetone 7)synthesis of propanone from an alcohol 8)addition of 3 moles H2 to benzene 9)formation of a cyanohydrin from 2-butanone 10)reaction of acetone with two moles CH3OH
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Aromatic Nitration QUESTIONS 1 Which compound in each of the following pairs is more reactive towards aromatic nitration? Expl your answers. a. phenol or nitrobenzene b. methyl benzoate or phenol c. nitrobenzene or methyl benzoate d. benzene or toluene 2. Show all possible mononitration products of toluene. Do you think it would be easy to isolate and identify all of them if each is produced in some amount? PRELABORATORY QUESTIONS 1. Lis three different combinations of reagents used for...