no of moles of CH3COOH = MOlarity* volume in L
= 0.671*0.625 = 0.4194 moles
PH = PKa + log[CH3COOK]/[CH3COOH]
5.77 = 4.76 + log[CH3COOK]/0.4194
5.77-4.76 = log[CH3COOK]/0.4194
1.01 = log[CH3COOK]/0.4194
[CH3COOK]/0.4194 = 101.01
[CH3COOK]/0.4194 = 10.23
[CH3COOK] = 10.23*0.4194
[CH3COOK] = 4.29
no of moles of CH3COOK = 4.29moles
no of moles of CH3COOK = no of moles of KOH
no of moles of KOH = 4.29 moles
volume of KOH = no of moles /molarity
= 4.29/2.12 = 2.023L = 2023ml = 2.023*103ml>>>> answer
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